Trimethyl phosphite as a trap for alkoxy radicals formed from the ring opening of oxiranylcarbinyl radicals. Conversion to alkenes. Mechanistic applications to the study of C-C versus C-O ring cleavage

Journal of the American Chemical Society

Volumn 125, Issue 11, 2003, Pages 3248-3259

  Ding, Bangwei ^a   Bentrude, Wesley G ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

RADICAL SYSTEMS;

CHEMICAL BONDS; DIMERIZATION; ETHERS; OLEFINS; REACTION KINETICS; THERMODYNAMICS;

SYNTHESIS (CHEMICAL);

ALCOHOL DERIVATIVE; ALKENE DERIVATIVE; CARBON; EPOXIDE; OXIRANYLCARBINYL RADICAL; PHOSPHITE; RADICAL; TRIMETHYL PHOSPHITE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; THERMAL ANALYSIS; THERMODYNAMICS;

ALCOHOLS; ALKENES; EPOXY COMPOUNDS; ETHYLENE OXIDE; FREE RADICAL SCAVENGERS; HYDROCARBONS, BROMINATED; OXIDATION-REDUCTION; PHOSPHITES;

EID: 0037454304     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja020761x     Document Type: Article

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