Kinetics of catalytic degradation of polycarbonate in benzene

Industrial and Engineering Chemistry Research

Volumn 42, Issue 4, 2003, Pages 687-691

  Sivalingam, G ^a   Nagaveni, K ^a   Madras, Giridhar ^a   Hegde, M S ^a  

^a INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDITY; ACTIVATION ENERGY; BENZENE; CATALYSIS; DEGRADATION; ENZYMES; GEL PERMEATION CHROMATOGRAPHY; MOLECULAR WEIGHT; SOLUTIONS; SYNTHESIS (CHEMICAL);

DISTRIBUTION KINETICS;

POLYCARBONATES;

4,4' ISOPROPYLIDENEDIPHENOL; BENZENE DERIVATIVE; PLATINUM; POLY(BISPHENOL A CARBONATE); POLYCARBONATE; TITANIUM DIOXIDE; UNCLASSIFIED DRUG;

BENZENE; DEGRADATION; KINETICS; POLYCARBONATE;

ACIDITY; ARTICLE; CATALYSIS; CATALYST; COMBUSTION; DEGRADATION; ENERGY; GEL PERMEATION CHROMATOGRAPHY; KINETICS; MODEL; MOLECULAR SIZE; MOLECULAR WEIGHT; NANOPARTICLE; REACTION ANALYSIS; REACTION TIME; TEMPERATURE DEPENDENCE; TIME;

EID: 0037454088     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020582o     Document Type: Article

References (25)

1. Miller, A. Industry Invests in Reusing plastics. Environ. Sci. Technol. 1994, 28, 16A.
2. Madras, G.; Smith, J. M.; McCoy, B. J. Degradation of Poly(methyl methacrylate) in Solution. Ind. Eng. Chem. Res. 1996, 35, 1795.
3. Karmore, V.; Madras, G. Continuous Distribution Kinetics of Degradation of Polystyrene in Supercritical Benzene. Ind. Eng. Chem. Res. 2000, 39, 4020.
4. Sivalingam, G.; Madras, G. Kinetics of Degradation of Polycarbonate in Supercritical and Subcritical Benzene. Ind. Eng. Chem. Res. 2002, 41, 5337.
5. Goto, M.; Koyamoto, H.; Kodama, A.; Hirose, T.; Nagaoka, S.; McCoy, B. J. Degradation Kinetics of Poly(ethylene terephthalate) in Supercritical Methanol. AIChE J. 2002, 48, 136.
6. Dhawan, J. C.; Legendre, R. C.; Bencsath, A. F.; Davies, R. M. Reaction Products of Styrene-Butadiene ABA Block Copolymer in Supercritical Toluene and Tetralin. J. Supercrit. Fluids 1991, 4, 160.
7. Kim, Y. C.; McCoy, B. J. Degradation Kinetics Enhancement of Polystyrene by Peroxide Addition. Ind. Eng. Chem. Res, 2000, 39, 2811.
8. Madras, G.; Smith, J. M.; McCoy, B. J. Effect of Tetralin on the Degradation of Polymer in Solution. Ind. Eng. Chem. Res. 1995, 34, 4222.
9. Madras, G.; Chattopadhyay, S. Effect of temperature and hydrogen donor on the degradation of poly(vinyl acetate). J. Appl. Polym. Sci. 2001, 81, 1996.
10. Park, D. W.; Hwang, E. Y.; Kim, J. R.; Choi, J. K.; Kim, Y. A.; Woo, H. C. Catalytic Degradation of Polyethylene over Solid Acid Catalysts, Polym. Degrad. Stab. 1999, 65, 193.
11. Mordi, R. C.; Fields, R.; Dwyer, J. Thermolysis of Low-Density Polyethylene Catalyzed by Zeolites. J. Anal. Appl. Pyrolysis 1994, 29, 45.
12. Uemichi, Y.; Kashiwaya, Y.; Ayame, A.; Kanoh, H. Chem. Lett. 1984, 41.
13. 2 Powder. Decarboxylic Route to Alkanes. J. Am. Chem. Soc. 1978, 100, 5985.
14. Sakata, T.; Kawai, T.; Hashimoto, K. Heterogeneous Photocatalytic Reactions of Organic Acids and Water. New Reaction Paths besides Photo-Kolbe Reaction. J. Phys. Chem. 1984, 88, 2344.
15. Ohtani, B.; Iwai, K.; Nishimoto, S.; Sato, S. Role of Platinum Deposits on Titanium(IV) Oxide Particles: Structural and Kinetic Analyses of Photocatalytic Reaction in Aqueous Alcohol and Amino Acid Solutions. J. Phys. Chem. B 1997, 101, 3349.
16. Sivalingam, G.; Radhika, M.; Rao, D. P.; Rao, M. S. Process Intensification in a Model Trickle Bed Reactor. Ind. Eng. Chem. Res. 2002, 41, 3139.
17. Tausker, S. J.; Fung, S. C.; Baker, R. T. K.; Horsley, J. A. Strong Interactions in Supported Metal Catalysts. Science 1981, 211, 1121.
18. Baker, R. T. K.; Prestridge, E. B.; Garten, R. L. Electron Microscopy of Supported Metal Particles I. Behavior of Pt on Titanium Oxide, Silicon Oxide and Carbon. J. Catal. 1979, 56, 390.
19. Evans, R. J.; Chum, H. L. Controlled Catalytic and Thermal Sequential Pyrolysis and Hydrolysis of Polycarbonate and Plastic Waste to Recover Monomers. Environ. Int. 1995, 21, XIII.
20. Blazso, M. Thermal Decomposition of Polymers Modified by Catalytic Effects of Copper and Iron Chlorides. J. Anal. Appl. Pyrolysis 1999, 51, 73.
21. Gonzalez, N.; Coll, P.; Aliev, R. Pyrolysis of γ-irradiated bisphenol A polycarbonate. Polym. Bull. 2002, 48, 43.
22. Gonzalez, N.; Aliev, R. Gaseous products formed by γ-irradiation of bisphenol A polycarbonate Polym. Bull. 2000, 45, 419.
23. Kodera, Y.; McCoy, B. J. Distribution Kinetics of Reversible Mechanisms: Reversible Polymer Decomposition. AIChE J. 1997, 43, 3205.
24. Batamack, P.; Doremieux-Morin, C.; Vincent, R.; Faissard, J. J. Phys. Chem. 1993, 97, 9779.
25. Boehm, H. P.; Herrmann, M. Z. Anorg. Chem. 1967, 352, 156.