Organic-inorganic hybrid zeolites containing organic frameworks

Science

Volumn 300, Issue 5618, 2003, Pages 470-472

  Yamamoto, Katsutoshi ^a,d   Sakata, Yasuyuki ^b   Nohara, Yuki ^c   Takahashi, Yoko ^c   Tatsumi, Takashi ^c  

^a UNIVERSITY OF TOKYO   (Japan)

^b Yokohama Laboratory   (Japan)

^c YOKOHAMA NATIONAL UNIVERSITY   (Japan)

^d TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; SILANES; SYNTHESIS (CHEMICAL);

LIPOPHILICITY;

ZEOLITES;

AMMONIUM DERIVATIVE; CARBENE; CARBON; INORGANIC COMPOUND; ORGANIC COMPOUND; ORGANOMETALLIC COMPOUND; OXYGEN; SILICON; TETRAPROPYLAMMONIUM; TETRYLAMMONIUM; ZEOLITE;

HYBRID; ORGANIC MATTER; ZEOLITE;

ADSORPTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CRYSTAL STRUCTURE; MATERIALS; PRIORITY JOURNAL; SYNTHESIS; TEMPERATURE; THERMAL ANALYSIS; X RAY DIFFRACTION;

EID: 0037453464     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1081019     Document Type: Article

References (29)

1. G. D. Stucky, J. E. MacDougall, Science 247, 669 (1990).
2. O. Terasaki, Solid State Phys. 27, 601 (1992).
3. S. D. Cox, T. E. Dier, G. D. Stucky, J. Bierlein. J. Am. Chem. Soc. 110, 2986 (1988).
4. N. Herron et al., J. Am. Chem. Soc. 111, 530 (1989).
5. U. Vietze, O. Krauß, F. Laeri, Phys. Rev. Lett. 81, 4628 (1998).
6. Y. Wada et al. J. Am. Chem. Soc. 122, 8583 (2000).
7. Y. Nozue, T. Kodaira, T. Goto, Phys. Rev. Lett. 68, 3789 (1992).
8. U. Simon, M. E. Franke, Micropor. Mesopor. Mater. 41, 1 (2000).
9. C. W. Jones, K. Tsuji, M. E. Davis, Nature 393, 52 (1998).
10. K. Tsuji, C. W. Jones, M. E. Davis, Micropor. Mesopor. Mater. 29, 339 (1999).
11. C. W. Jones, K. Tsuji, M. E. Davis, Micropor. Mesopor. Mater. 33, 223 (1999).
12. C. W. Jones, M. Tsapatsis, T. Okubo, M. E. Davis, Micropor. Mesopor. Mater. 42, 21 (2001).
13. K. Yamamoto, Y. Takahashi, T. Tatsumi, Stud. Surf. Sci. Catal. 135, 299 (2001).
14. K. J. Shea, D. A. Loy, O. W. Webster, Chem. Mater. 1, 572 (1989).
15. R. J. P. Corriu, J. J. E. Moreau, P. Thepot, M. W. C. Man, Chem. Mater. 4, 1217 (1992).
16. S. Inagaki, S. Guan, Y. Fukushima, T. Ohsuna, O. Terasaki, J. Am. Chem. Soc. 121, 9611 (1999).
17. B. J. Melde, B. T. Holland, C. F. Blanford, A. Stein, Chem. Mater. 11, 3302 (1999).
18. T. Asefa, M. J. MacLachlan, N. Coombs, G. A. Ozin, Nature 402, 867 (1999).
19. Y. Lu et al., J. Am. Chem. Soc. 122, 5258 (2000).
20. 2 group is also larger than an O atom (the typical Si-C bond length is 1.88 Å and Si-O bond lengths in zeolites about 1.6 Å), small Si-C-Si angles (∼109°) compared with typical Si-O-Si angles (140° to 160°) would compensate for the distance of two Si atoms to maintain the crystalline structure.
21. Materials and methods are available as supporting material on Science Online.
22. The unit cell parameters of ZOL-1 were calculated with the program DLS-76.
23. T. Blasco et al., Chem. Commun. 1996, 2367 (1996).
24. F. Y. Dai, K. Deguchi, M. Suzuki, H. Takahashi, Y. Saito, Chem. Lett. 1988, 869 (1988).
25. H. Robson, K. P. Lillerud, Eds., Verified Synthesis of Zeolitic Materials (Elsevier, Amsterdam, ed. 2, 2001), pp. 179-181.
26. 0.5 containing 10.2 wt% of carbon.
27. 1H for methylene and methine groups diminish so quickly compared with the interaction for the methyl group that the signals derived from methylene and methine groups practically disappear within 100 μs.
28. When ZOL-B is calcined at 450°C, the T-type peak is mostly (96%) retained, and the occluded SDA is completely removed simultaneously.
29. 29Si MAS NMR, and Y. Domon for assistance in synthesizing the materials. Supported by Core Research for Evolutional Science and Technology of the Japan Science and Technology Corporation.