Iron twin-coronet porphyrins as models of myoglobin and hemoglobin: Amphibious electrostatic effects of overhanging hydroxyl groups for successful CO/O2 discrimination

Chemistry - A European Journal

Volumn 9, Issue 4, 2003, Pages 862-870

  Tani, Fumito ^a   Matsu ura, Mikiya ^a   Ariyama, Kiyoko ^a   Setoyama, Toshikazu ^a   Shimada, Takayuki ^b   Kobayashi, Shinjiro ^a   Hayashi, Takashi ^a   Matsuo, Takashi ^a   Hisaeda, Yoshio ^a   Naruta, Yoshinori ^a  

^a KYUSHU UNIVERSITY   (Japan)

^b KINKI UNIVERSITY   (Japan)

Author keywords

Dioxygen ligands; Electrostatic interactions; Heme proteins; Hydrogen bonds; Porphyrinoids

Indexed keywords

BONDING; COBALT COMPOUNDS; ELECTROSTATICS; HEMOGLOBIN; HYDROPHOBICITY; HYDROXYLATION; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE; PORPHYRINS; RAMAN SPECTROSCOPY; SYNTHESIS (CHEMICAL); ULTRAVIOLET SPECTROSCOPY;

POLAR INTERACTIONS;

IRON;

CARBON DIOXIDE; HEME; HEMOGLOBIN; HYDROXYL GROUP; MYOGLOBIN; NAPHTHYL GROUP; OXYGEN; PORPHYRIN;

ARTICLE; COMPLEX FORMATION; COVALENT BOND; ELECTRIC ACTIVITY; HYDROGEN BOND; HYDROPHOBICITY; INFRARED SPECTROSCOPY; KINETICS; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE; OXYGEN AFFINITY; PROTEIN STRUCTURE; RAMAN SPECTROMETRY; REACTION ANALYSIS; STEREOSPECIFICITY; SYNTHESIS; THERMODYNAMICS; ULTRAVIOLET SPECTROSCOPY;

ALGORITHMS; CARBON MONOXIDE; ELECTROCHEMISTRY; HEMOGLOBINS; INDICATORS AND REAGENTS; KINETICS; MODELS, CHEMICAL; MODELS, MOLECULAR; MYOGLOBIN; OXYGEN; PORPHYRINS; SPECTROPHOTOMETRY, INFRARED; THERMODYNAMICS;

EID: 0037450044     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200390096     Document Type: Article

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