Retention of metal ions in ultrafiltration of mixtures of divalent metal ions and water-soluble polymers at constant ionic strength based on Freundlich and Langmuir isotherms

Journal of Membrane Science

Volumn 215, Issue 1-2, 2003, Pages 195-202

  Moreno Villoslada, Ignacio ^a   Rivas, Bernabé L ^b  

^a UNIVERSIDAD AUSTRAL DE CHILE   (Chile)

^b UNIVERSITY OF CONCEPCIÓN   (Chile)

Author keywords

Retention profiles; Ultrafiltration; Water soluble polymers metal ion interactions

Indexed keywords

ADSORPTION ISOTHERMS; FRACTIONATION; IONIC STRENGTH; ULTRAFILTRATION;

WATER-SOLUBLE POLYMERS;

POLYMERS;

CADMIUM; METAL ION; NICKEL; POLY(ALLYLAMINE); POLY(SODIUM 4 STYRENESULFONATE); POLYETHERSULFONE; POLYMER; UNCLASSIFIED DRUG; WATER;

ION EXCHANGE; MEMBRANE TECHNOLOGY; POLYMER; ULTRAFILTRATION;

ADSORPTION; ARTICLE; ARTIFICIAL MEMBRANE; CHEMICAL INTERACTION; IONIC STRENGTH; ISOTHERM; MATHEMATICAL ANALYSIS; METHODOLOGY; MOLECULAR WEIGHT; PRIORITY JOURNAL; ULTRAFILTRATION;

EID: 0037446090     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(02)00613-0     Document Type: Article

References (25)

1. Tsuchida E., Nishide H. Polymer-metal complexes and their catalytic activity. Adv. Polym. Sci. 24:1977;1.
2. Ustamehmetoglu B., Bayülken S., Özkara S., Sönmez G., Saraç A.S. Interaction of metal ions with polypyrrole on polyacrylic acid matrix. J. Polym. Sci. A: Polym. Chem. 37:1999;1115.
3. Carambassis A., Rutland M.W. Interactions of cellulose surfaces: effect of electrolyte. Langmuir. 15:1999;5584.
4. Jarvis N.V., Wagener J.M. Mechanistic studies of metal ion binding to water-soluble polymers using potentiometry. Talanta. 42:1995;219.
5. Hamaya T., Hiratani K., Ohashi K. Ultraviolet spectrophotometric studies of the reactivity of a water-soluble polymer containing pendant 8-hydroxyquinoline moieties with metal ions. Macromol. Chem. Phys. 195:1994;2739.
6. Manning G.S. The molecular theory of polyelectrolyte solutions with applications to the electrostatic properties of polynucleotides. Q. Rev. Biophys. 11:1978;179.
7. Manning G.S. Limiting laws and counterion condensation in polyelectrolyte solutions. 8. Mixtures of counterions, species selectivity, and valence selectivity. J. Phys. Chem. 88:1984;6654.
8. Nordmeier E. Advances in polyelectrolyte research: counterion binding phenomena, dynamic processes, and the helix-coil transition of DNA. Macromol. Chem. Phys. 196:1995;1321.
9. Nordmeier E., Dauwe W. Studies on polyelectrolyte solutions. I. Counterion condensation by poly(styrenesulfonate). Polym. J. 23:1991;1297.
10. Riedl C., Qian C., Savitsky G.B., Spencer H.G., Moss W. Mathematical modeling of the concentration dependence of competitive binding of counterions in polyelectrolytes. Macromolecules. 22:1989;3983.
11. Gregor H.P., Gregor J.M. Coulombic reactions of polyelectrolytes with counterions of different sizes. J. Chem. Phys. 66:1977;1934.
12. Winkler R.G., Gold M., Reineker P. Collapse of polyelectrolyte macromolecules by counterion condensation and ion pair formation: a molecular dynamics simulation study. Phys. Rev. Lett. 80:1998;3731.
13. Hao M.H., Harvey S.C. A lattice theory for counterion binding on polyelectrolytes. Macromolecules. 25:1992;2200.
14. Paoletti S., Benegas J., Cesáro A., Manzini G., Fogolari F., Crescenzi V. Limiting-laws of polyelectrolyte solutions. Ionic distribution in mixed-valencey counterions systems. I. The model. Biophys. Chem. 41:1991;73.
15. Dewey T.G. A ligand binding model of counterions condensation to finite length polyelectrolytes. Biopolymers. 29:1990;1793.
16. Tomida T., Inoue T., Tsuchiya K., Masuda S. Concentration and/or removal of metal ions using a water-soluble chelating polymer and a microporous hollow fiber membrane. Ind. Eng. Chem. Res. 33:1994;904.
17. Geckeler K.E., Lange G., Eberhardt H., Bayer E. Preparation and application of water-soluble polymer-metal complexes. Pure Appl. Chem. 52:1980;1883.
18. Rivas B.L., Geckeler K.E. Synthesis and metal complexation of poly(ethyleneimine) and derivatives. Adv. Polym. Sci. 102:1992;171.
19. Uludag Y., Özbelge H.Ö., Yilmaz L. Removal of mercury from aqueous solutions via polymer-enhanced ultrafiltration. J. Membr. Sci. 129:1997;93.
20. Rivas B.L., Moreno-Villoslada I. Prediction of the retention values associated to the ultrafiltration of mixtures of metal ions and high molecular weight water-soluble polymers as a function of the initial ionic strength. J. Membr. Sci. 178:2000;165.
21. Rivas B.L., Moreno-Villoslada I. Poly[acrylamide-co-1-(2-hydroxyethyl)aziridine]: an efficient water-soluble polymer for selective separation of metal ions. J. Appl. Polym. Sci. 69:1998;817.
22. Rivas B.L., Pereira E., Martínez E., Moreno-Villoslada I. Metal ion interactions with poly(2-acrylamide-2-methyl-1-propanesulfonic acid-co-methacrylic acid. Bol. Soc. Chil. Quim. 45:2000;199.
23. + ions by poly(sodium 4-styrenesulfonate) analyzed by ultrafiltration and its relation with the counterion condensation theory. J. Phys. Chem. B. 102:1998;6994.
24. +. J. Phys. Chem. B. 102:1998;11024.
25. Rivas B.L., Seguel G.V. Synthesis, characterization of poly(allylamine) chelates with Cu(II), Co(II), and Ni(II). Polym. Bull. 37:1996;463.