Competitive absorption of quaternary ammonium and alkali metal cations into a Nafion cation-exchange membrane

Journal of Membrane Science

Volumn 215, Issue 1-2, 2003, Pages 103-114

  Palomo, Joaquin ^a,c   Pintauro, Peter N ^a,b  

^a Tulane University   (United States)

^b Case Western Reserve University   (United States)

^c T3 Inc   (United States)

Author keywords

Alkali metal cations; Cation exchange membranea; Quaternary ammonium

Indexed keywords

ABSORPTION; ALKALI METALS; AMMONIUM COMPOUNDS; HYDRATION; POSITIVE IONS; SALTS;

PARTITION COEFFICIENT THEORY;

ION EXCHANGE MEMBRANES;

ALKALI METAL; CATION; CESIUM; LITHIUM; QUATERNARY AMMONIUM DERIVATIVE; SODIUM;

ADSORPTION; ALKALI; AMMONIUM COMPOUND; ION EXCHANGE; MEMBRANE TECHNOLOGY; SALT;

ABSORPTION; ACCURACY; AQUEOUS SOLUTION; ARTICLE; CALCULATION; CATION EXCHANGE; CATION EXCHANGE MEMBRANE; CONCENTRATION RESPONSE; EQUILIBRIUM CONSTANT; HYDRATION; MEMBRANE; PRIORITY JOURNAL; RACEMIC MIXTURE; THEORETICAL MODEL;

EID: 0037446027     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(02)00606-3     Document Type: Article

References (22)

1. Bontha J.T., Pintauro P.N. Water orientation and ion hydration effects during multicomponent salt partitioning in a Nafion 117 cation exchange membrane. Chem. Eng. Sci. 49:1994;3835.
2. Pintauro P.N., Tandon R., Chao L., Xu W., Evilia R. Equilibrium partitioning of monovalent/divalent cation-salt mixtures in Nafion cation-exchange membranes. J. Phys. Chem. 99:1995;12915.
3. Tandon R., Pintauro P.N. Divalent/monovalent cation uptake selectivity in a Nafion cation-exchange membrane: experimental and modeling studies. J. Membr. Sci. 136:1997;207.
4. D. Pletcher, F.C. Walsh, Industrial Electrochemistry, Chapman and Hall, London, 1982, pp. 298-304.
5. Martin C.R., Freiser H. Ion-selective electrodes based on an ionic polymer. Anal. Chem. 53:1981;902.
6. Szentirmay M.N., Martin C.R. Ion-exchange selectivity of Nafion films on electrode surfaces. Anal. Chem. 56:1984;1898.
7. White H.S., Leddy J., Bard A. Polymer films on electrodes. 8. Investigation of charge-transport mechanisms in Nafion polymer modified electrodes. J. Am. Chem. Soc. 104:1982;4811.
8. Martin C.R., Dollard K.A. Effect of hydrophobic interactions on the rates of ionic diffusion in Nafion films at electrode surfaces. J. Electroanal. Chem. Interf. Electrochem. 159:1983;127.
9. Booth F.J. The dielectric constant of water and saturation effect. J. Chem. Phys. 19:1951;391.
10. Goldschmidt N.M. Krystallban und chemische zusammensetzung. Chem. Ber. 60:1927;1263.
11. Bondi A. Van der Waals volumes and radii. J. Phys. Chem. 68:1964;441.
12. Landolt-Börnstein numerical data and fundamental relationships in science and technology, group II: atomic and molecular physics, in: K.H. Helhuege (Ed.), Structure Data of Free Polyatomic Molecules, vol. 7, Springer, New York, 1976.
13. Garde S., Hummer G., Paulaitis M.E. Free energy of hydration of a molecular ionic solute: tetramethylammonium ion. J. Chem. Phys. 108:1998;1552.
14. Halliwell H.F., Newberg S.C. Enthalpy of hydration of the proton. Trans. Farad. Soc. 59:1963;1126.
15. Rossiensky D.R. Electrode potentials and hydration energies. Chem. Rev. 65:1965;467.
16. Abraham M.H., Liszi J. Calculations on ionic solvation. Part 1. Free energies of solvation of gaseous univalent ions using a one-layer continuum model. J. Chem. Soc., Faraday Trans. I. 74:1978;1604.
17. H.L. Friedman, C.V. Krishnan, Thermodynamics of ionic hydration, in: F. Franks (Ed.), Water - A Comprehensive Treatise, Plenum Press, New York, 1973, pp. 1-118.
18. Deen W.M. Hindered transport of large molecules in liquid-filled pores. AIChE J. 33:1987;1409.
19. T.D. Gierke, W.Y. Hsu, The cluster-network model of ion clustering in perfluorosulfonated membranes, in: A. Eisenberg, H.L. Yeager (Eds.), Perfluorinated Ionomer Membranes, ACS Symposium Series No. 180, American Chemical Society, Washington, DC, 1982, pp. 283-307.
20. Pintauro P.N., Bennion D.N. Mass transport of electrolytes in membranes. II. Determination of equilibrium and transport parameters for Nafion. Ind. Eng. Chem. Fundam. 23:1984;234.
21. Verbrugge M.W., Hill R.F. Experimental and theoretical investigation of perfluorosulfonic acid membranes with aqueous sulfuric acid solutions. J. Phys. Chem. 92:1988;6778.
22. T.D. Gierke, G.E. Munn, F.C. Wilson, Morphology of perfluorosulfonated membrane products: wide angle and small angle X-ray studies, in: A. Eisenberg, H.L. Yeager (Eds.), Perfluorinated Ionomer Membranes, ACS Symposium Series No. 180, American Chemical Society, Washington, DC, 1982, pp. 195-216.