Optically active transition metal complexes. Part 131. Synthesis and epimerization of chiral-at-metal (η6-arene)ruthenium(II) and (η6-arene)osmium(II) half-sandwich complexes

Polyhedron

Volumn 22, Issue 6, 2003, Pages 861-865

  Brunner, Henri ^a   Zwack, Thomas ^a   Zabel, Manfred ^a  

^a UNIVERSITY OF REGENSBURG   (Germany)

Author keywords

Chiral at metal complexes; Configurational stability; Diastereomer equilibria; Epimerization; X ray structure analyses

Indexed keywords

CHELATION; ISOMERS; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

CHIRAL-AT-METAL COMPLEX; CONFIGURATIONAL STABILITY; DIASTEREOMER EQUILIBRIUM; DIASTEREOMERS; EPIMERIZATION; OPTICALLY ACTIVE; P-CYMENE; STRUCTURE ANALYSIS; X-RAY STRUCTURE; X-RAY STRUCTURE ANALYZE;

METAL COMPLEXES;

CYMENE; LIGAND; METAL COMPLEX; N,N DIMETHYL (1 PHENYLETHYL)AMINE; OSMIUM DERIVATIVE; POLYCYCLIC AROMATIC HYDROCARBON; RUTHENIUM COMPLEX; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; CRYSTALLIZATION; DIASTEREOISOMER; EPIMERIZATION; INFRARED SPECTROSCOPY; MELTING POINT; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY ANALYSIS;

EID: 0037443928     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(02)01424-9     Document Type: Article

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