Preparation and spectroscopic characterization of surface-enriched (with active sites) polymer-supported phase-transfer catalysts and their efficiency in organic addition reactions: A kinetic study

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 41, Issue 2, 2003, Pages 347-364

  Balakrishnan, T ^a   Murugan, E ^a  

^a UNIVERSITY OF MADRAS   (India)

Author keywords

Delayed addition; Partial polymerization; Polymer supported phase transfer catalysts; Semiquantitative; Surface grafting; Surface enriched (with active sites)

Indexed keywords

ADDITION REACTIONS; CROSSLINKING; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FREE RADICALS; GRAFTING (CHEMICAL); MONOMERS; PHASE TRANSITIONS; POLYMERIZATION; REACTION KINETICS; SCANNING ELECTRON MICROSCOPY;

PHASE-TRANSFER CATALYSTS;

CATALYSTS;

KINETICS; POLYMER SCIENCE;

EID: 0037438847     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.10562     Document Type: Article

References (69)

1. Jarrouse, J. C R Hebd Seances Acad Sci Ser C 1951, 232, 1424.
2. Regen, S. L. J Am Chem Soc 1975, 97, 5956.
3. Cinouini, M.; Colonna, S.; Molinari, H.; Tundoand, P.; Montanary, F. J Chem Soc Chem Commun 1976, 394.
4. Molinari, H.; Montanari, F.; Quici, S.; Tundo, P. J Am Chem Soc 1979, 101, 3920.
5. Montanari, F.; Tundo, P. J Org Chem 1981, 46, 2125.
6. Brown, J. M.; Jenkins, J. A. J Chem Soc Chem Commun 1976, 458.
7. Ohtani, N.; Wilkie, C. A.; Nigam, A.; Regen, S. L. Macromolecules 1981, 14, 516.
8. Chaudhari, R. V.; Ramachandran, P. A. AIChE J 1980, 26, 177.
9. Marconi, D. F.; Ford, W. T. J Catal 1983, 1, 163-167.
10. Ford, W. T.; Balakrishnan, T. Macromolecules 1981, 54, 575.
11. Ford, W. T.; Yacoub, S. A. J Org Chem 1981, 46, 819.
12. Balakrishnan, T.; Ford, W. T. J Appl Polym Sci 1982, 27, 13.
13. Balakrishnan, T.; Ford, W. T. J Org Chem 1983, 48, 1029.
14. Balakrishnan, T.; Ford, W. T. Tetrahedron Lett 1983, 4377.
15. Balakrishnan, T.; Haribabu, S.; Perumal, A. J Polym Sci Part A: Polym Chem 1990, 28, 1421.
16. Regen, S. L.Angew Chem Int Ed Engl 1979, 18, 421.
17. Sherrington, D. C. Polymer Supported Reactions in Organic Synthesis; Wiley: New York, 1980.
18. MClinari, H.; Montanari, F.; Quici, F.; Tundo, S. J Am Chem Soc 1979, 101, 3920.
19. Regen, S. L. J Am Chem Soc 1976, 98, 6270.
20. Regen, S. L.; Besse, J. J. J Am Chem Soc 1979, 101, 4059.
21. Tomoi, M.; Ford, W. T. J Am Chem Soc A 1981, 103, 3821.
22. Tomoi, M.; Ford, W. T. J Am Chem Soc B 1981, 103, 3828.
23. Solaro, R.; Dantone, D.; Chiellnii, E. React Polym 1988, 9, 155.
24. Regen, S. L.; Balikal, D.; Barcelon, C. J Org Chem 1981, 46, 2511.
25. Tomoi, M.; Ogawa, E.; Hosokana, Y.; Kakiuchi, H. J Polym Sci Polym Chem Ed 1982, 20, 3421.
26. Tomoi, M.; Nakamura, E.; Hosokawa, Y.; Kakiuchi, Y. J Polym Sci Polym Chem Ed 1985, 23, 49.
27. Chiles, M. S.; Jackson, D. D.; Reeva, P. C. J Org Chem 1980, 45, 2915.
28. Regen, S. L. Nouv J Chem 1982, 6, 629.
29. Wang, M.-L.; Yang, H.-M. Ind Eng Chem Res 1992, 31, 1868.
30. Wang, M.-L.; Wu, H.-S. Chem Eng Sci 1991, 46, 509.
31. Fitch, R. M.; Gajra, G.; Tarcha, P. J. J Colloid Interface Sci 1979, 71, 107.
32. Sherrington, D. C.; Hodge, P. Syntheses and Separations Using Functional Polymers; Wiley: New York, 1988; p 46.
33. Sherrington, D. C.; Hodge, P. Syntheses and Separation Using Functional Polymers; Wiley: New York, 1998; p 30.
34. Ford, W. I.; Periyasamy, M.; Spivey. H. O. Macromolecules 1974, 96, 5275.
35. Matera, V. D.; Squattrito, P. J.; Risen, W. M. Inorg Chem 1984, 23, 3597.
36. Shim, I.; Mattera,V. D.; Risen, W. M. J Catal 1985, 94, 531.
37. Barnes, B. D. M.; Chaudhuri, S. N.; Chryssikos, G. D.; Mattera, V. D.; Peluso, S. L.; Shim, I. W.; Tsatsas, A. T.; Risen, W. M. In Coulombic Interactions in Macromolecular Systems; Eisenberg, A.; Bailey, F. E., Eds.; ACS Symposium Series 302; American Chemical Society: Washington, DC, 1986; p 66.
38. Kita, R.; Svec, F.; Frechet, J. M. J. J Comb Chem 2001, 3, 564-571.
39. Svec, F.; Petro, M.; Frechet, J. M. J. Chem Commun 2001, 66, 1047-1061.
40. Quas, G.; Roch, A. M.; Niveleau, A. J Immunol Methods 1982, 22, 165.
41. Ficher, E. A. Br. Pat. Appl. GB2027031 A, 1978.
42. Dorman, L. C. U.S. Patent 4,421,896, 1983.
43. Molinari, H.; Montanari, F.; Quinci, S.; Tundo, P. J Am Chem Soc 1979, 101, 3920.
44. Molinari, H.; Montanari, F.; Quinci, S.; Tundo, P. J Chem Soc Chem Commun 1977, 639.
45. Sherrington, D. C.; Hodge, P. Syntheses and Separations Using Functional Polymers; Wiley: New York, 1988; p 31.
46. Tomoi, M.; Ford, W. T. J Am Chem Soc 1980, 102, 714.
47. Tomoi, M.; Ford, W. T. J Am Chem Soc 1981, 103, 382.
48. Sherrington, D. C.; Hodge, P. Syntheses and Separations Using Functional Polymers; Wiley: New York, 1988; p 46.
49. Guyot, A.; Bartholin. M. Prog Polym Sci 1982, 8, 277.
50. Schutten, J. H.; Van Hastenberg, C. H.; Piet, P.; German, A. L. Angew Macromol Chem 1980, 89, 201.
51. Balakrishnan, T.; Murugan, E. J Appl Polym Sci 2000, 76, 408.
52. Balakrishnan, T.; Rajendran, V. J Polym Sci Part A: Polym Chem 1997, 35, 1.
53. Arshady, R.; Reddy, B. S. R.; George, M. Macromolecules 1983, 16, 1813.
54. Narasimhaswamy, T.; Devasagayam, G.; Sumathi, S. G.; Reddy, B. S. R. Polym Int 1992, 27, 75.
55. Narasimhaswamy, T.; Sumathi, S. C.; Reddy, B. S. R.; Rajadurai, S. Polymer Science Contemporary Themes; Sivaram, S., Ed.; Tata-MCGraw Hill: New Delhi, 1991; p 416; Chem Abstr 1991, 155, 723312.
56. Narasimhaswamy, T.; Sumathi, S. C.; Reddy, B. S. R.; Rajadurai, S. Polymer Science Contemporary Themes; Sivaram, S., Ed.; Tata-MCGraw Hill: New Delhi, 1991; p 416; Chem Abstr 1991, 155, 723312.
57. Reddy, B. S. R.; Narasimhaswamy, T. J Appl Polym Sci 1991, 43, 1645.
58. Hong, L.; Ruckenstein, E. Polymer 1992, 33, 1968.
59. Dyer, J. R. Application of Absorption Spectroscopy of Organic Compounds; Prentice Hall of India, Ltd.: New Delhi, India, 1991.
60. Silverstain, R. M.; Bassler, G. C.; Morrill, T. C. Spectroscopic Identification of Organic Compounds, 4th ed.; Wiley: New York, 1981.
61. Ruckenstein, E.; Hong, L. J Catal 1992, 136, 378.
62. Chou, S.; Sham Weng, H. J Appl Polym Sci 1990, 39, 1665.
63. Jabbari, E.; Nikolaos Peppas, A. J Appl Polym Sci 1995, 57, 775.
64. Carlson, T. A. Photoelectron and Augers Spectroscopy; Plenum: New York, 1975.
65. Glosh, P. K. Introduction to Photoelectron Spectroscopy; Wiley-Interscience: New York, 1983.
66. Antony, M. T. Chem Br 1986, 111, 33.
67. Wanger, C. D.; Riggs, W. M.; Davis, L. E.; Moulder, J. F.; Muilenberg, G. E. Hand Book of X-Ray Photoelectron Spectroscopy; PerkinElmer Corporation: Minnesota, 1978.
68. Adem, E. XPS Hand Book; V.G. Scientific Instruments: West Sussex, UK, 1981.
69. XPS and AUGER Hand Book; Fisons V. G. Scientific Instruments: West Sussex, UK, 1985.