메뉴 건너뛰기




Volumn 100, Issue 1-3, 2002, Pages 205-220

New considerations of the Barclay-Butler rule and the behavior of water dissolved in organic solvents

Author keywords

Enthalpy entropy compensation; Entropy of vaporization; Solvation; Solvent structure; Thermodynamics of solution transfer

Indexed keywords

PROTEIN; WATER;

EID: 0037438637     PISSN: 03014622     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0301-4622(02)00282-X     Document Type: Article
Times cited : (15)

References (50)
  • 1
    • 0001059367 scopus 로고
    • The entropy of solution
    • and references therein
    • Barclay M., Butler J.A. The entropy of solution. Trans. Faraday Soc. 34:1938;1445-1454 and references therein.
    • (1938) Trans. Faraday Soc. , vol.34 , pp. 1445-1454
    • Barclay, M.1    Butler, J.A.2
  • 2
    • 0001625040 scopus 로고
    • Free volume and entropy in condensed systems. Part II. Entropy of vaporization in liquids and the pictorial theory of the liquid state
    • Frank H.S. Free volume and entropy in condensed systems. Part II. Entropy of vaporization in liquids and the pictorial theory of the liquid state. J. Chem. Phys. 13:(11):1945;493-507.
    • (1945) J. Chem. Phys. , vol.13 , Issue.11 , pp. 493-507
    • Frank, H.S.1
  • 3
    • 0035107447 scopus 로고    scopus 로고
    • Entropy-enthalpy compensation: Fact or artifact
    • Sharp K. Entropy-enthalpy compensation: fact or artifact. Protein Sci. 10:2001;661-667.
    • (2001) Protein Sci. , vol.10 , pp. 661-667
    • Sharp, K.1
  • 4
    • 36849117971 scopus 로고
    • Free volume and entropy in condensed systems. Part III. Entropy in binary liquid mixtures; Partial molal entropy in dilute solutions; Structure and thermodynamics in aqueous electrolytes
    • Frank H.S., Evans M.S. Free volume and entropy in condensed systems. Part III. Entropy in binary liquid mixtures; partial molal entropy in dilute solutions; structure and thermodynamics in aqueous electrolytes. J. Chem. Phys. 13:(11):1945;507-531.
    • (1945) J. Chem. Phys. , vol.13 , Issue.11 , pp. 507-531
    • Frank, H.S.1    Evans, M.S.2
  • 6
    • 3943103200 scopus 로고
    • Standard thermodynamics of transfer
    • Ben-Naim A. Standard thermodynamics of transfer. J. Phys. Chem. 82:(71):1978;792-803.
    • (1978) J. Phys. Chem. , vol.82 , Issue.71 , pp. 792-803
    • Ben-Naim, A.1
  • 8
    • 0026189146 scopus 로고
    • A molecular dynamics study of thermodynamic and structural aspects of the hydration of cavities in proteins
    • Wade R.C., Mazor M.H., McCammon J.A., Quiocho F.A. A molecular dynamics study of thermodynamic and structural aspects of the hydration of cavities in proteins. Biopolymers. 31:1991;919-931.
    • (1991) Biopolymers , vol.31 , pp. 919-931
    • Wade, R.C.1    Mazor, M.H.2    McCammon, J.A.3    Quiocho, F.A.4
  • 15
    • 33645903407 scopus 로고
    • Solvation thermodynamics of non-ionic solutes
    • Ben-Naim A., Marcus Y. Solvation thermodynamics of non-ionic solutes. J. Chem. Phys. 81:(4):1984;2016-2027.
    • (1984) J. Chem. Phys. , vol.81 , Issue.4 , pp. 2016-2027
    • Ben-Naim, A.1    Marcus, Y.2
  • 18
    • 33845556138 scopus 로고
    • Simulation of liquid ethanol including internal rotations
    • Jorgensen W.L. Simulation of liquid ethanol including internal rotations. J. Am. Chem. Soc. 103:1981;345-350.
    • (1981) J. Am. Chem. Soc. , vol.103 , pp. 345-350
    • Jorgensen, W.L.1
  • 19
    • 0000291225 scopus 로고
    • Optimized intermolecular potential functions for liquid alcohols
    • Jorgensen W.L. Optimized intermolecular potential functions for liquid alcohols. J. Phys. Chem. 90:(7):1986;1276-1284.
    • (1986) J. Phys. Chem. , vol.90 , Issue.7 , pp. 1276-1284
    • Jorgensen, W.L.1
  • 20
    • 33845556487 scopus 로고
    • A random network model for water
    • and references therein
    • Sceats M.G., Rice S.A. A random network model for water. J. Phys. Chem. 85:1981;1108 and references therein.
    • (1981) J. Phys. Chem. , vol.85 , pp. 1108
    • Sceats, M.G.1    Rice, S.A.2
  • 21
    • 0001332057 scopus 로고
    • Equation of state of a random network, continuum model of liquid water
    • Henn A.R., Kauzmann W. Equation of state of a random network, continuum model of liquid water. J. Phys. Chem. 93:1989;3770-3783.
    • (1989) J. Phys. Chem. , vol.93 , pp. 3770-3783
    • Henn, A.R.1    Kauzmann, W.2
  • 22
    • 9344263550 scopus 로고
    • Thermodynamic functions of the solubilities of gases in liquids at 25°C
    • Wilhelm E., Battino R. Thermodynamic functions of the solubilities of gases in liquids at 25°C. Chem. Rev. 73:(1):1973;1-9.
    • (1973) Chem. Rev. , vol.73 , Issue.1 , pp. 1-9
    • Wilhelm, E.1    Battino, R.2
  • 25
    • 0000013706 scopus 로고
    • An equation of state describing hydrophobic interactions
    • Gill S.J., Wadso I. An equation of state describing hydrophobic interactions. Proc. Natl. Acad. Sci. USA. 73:(9):1976;2955-2958.
    • (1976) Proc. Natl. Acad. Sci. USA , vol.73 , Issue.9 , pp. 2955-2958
    • Gill, S.J.1    Wadso, I.2
  • 26
    • 33847088763 scopus 로고
    • Low-pressure solubility of gases in liquid water
    • Wilhelm E., Battino R., Wilcock R.J. Low-pressure solubility of gases in liquid water. Chem. Rev. 77:(2):1977;219-262.
    • (1977) Chem. Rev. , vol.77 , Issue.2 , pp. 219-262
    • Wilhelm, E.1    Battino, R.2    Wilcock, R.J.3
  • 28
    • 84986550271 scopus 로고
    • Thermodynamics of ionization and solutions of aliphatic amines in water
    • A. Streitwieser, & R.W. Taft. New York: John Wiley
    • Jones F.M. III, Arnett E.M. Thermodynamics of ionization and solutions of aliphatic amines in water. Streitwieser A., Taft R.W. Progress in Physical Organic Chemistry, vol. 11. 1974;263-322 John Wiley, New York.
    • (1974) Progress in Physical Organic Chemistry, vol. 11 , pp. 263-322
    • Jones F.M. III1    Arnett, E.M.2
  • 29
    • 0028093141 scopus 로고
    • On the probability of finding a water molecule in a non-polar cavity
    • Wolfenden R., Radzicka A. On the probability of finding a water molecule in a non-polar cavity. Science. 265:1994;936-937.
    • (1994) Science , vol.265 , pp. 936-937
    • Wolfenden, R.1    Radzicka, A.2
  • 31
    • 37049119497 scopus 로고
    • The molecular complexity of water in organic solvents, Part III
    • J.R. Johnson, S.D. Christian, H.E. Affsprung. The molecular complexity of water in organic solvents, Part III. J. Chem. Soc. A. (1967) 1924-1928.
    • (1967) J. Chem. Soc. A. , pp. 1924-1928
    • Johnson, J.R.1    Christian, S.D.2    Affsprung, H.E.3
  • 32
    • 0002424536 scopus 로고
    • Molecular complexes of water in organic solvents and in the vapor phase
    • Christian S.D., Taha A.A., Gash B.W. Molecular complexes of water in organic solvents and in the vapor phase. J. Chem. Soc. Q. Rev. 24:1974;20-36.
    • (1974) J. Chem. Soc. Q. Rev. , vol.24 , pp. 20-36
    • Christian, S.D.1    Taha, A.A.2    Gash, B.W.3
  • 33
    • 0001762440 scopus 로고
    • The determination and statistical mechanical interpretation of the solubility of water in benzene, carbon tetrachloride, and cyclohexane
    • Goldman S. The determination and statistical mechanical interpretation of the solubility of water in benzene, carbon tetrachloride, and cyclohexane. Can. J. Chem. 52:1974;1668-1680.
    • (1974) Can. J. Chem. , vol.52 , pp. 1668-1680
    • Goldman, S.1
  • 34
    • 33646523709 scopus 로고
    • Solubilities of water in several normal alkanes from C7 to C16
    • Schatzberg P. Solubilities of water in several normal alkanes from C7 to C16. J. Phys. Chem. 67:1963;776-779.
    • (1963) J. Phys. Chem. , vol.67 , pp. 776-779
    • Schatzberg, P.1
  • 35
    • 0000532431 scopus 로고
    • The solubility of water in hydrocarbons
    • Black C., Joris G.C., Taylor H.S. The solubility of water in hydrocarbons. J. Chem. Phys. 16:(5):1948;537-543.
    • (1948) J. Chem. Phys. , vol.16 , Issue.5 , pp. 537-543
    • Black, C.1    Joris, G.C.2    Taylor, H.S.3
  • 36
    • 0001372863 scopus 로고
    • Mutual solubilities of hydrocarbons and water at 25°C
    • The solubilities of water in various organic solvents were measured at only two temperatures, 0 and 25°C, but we considered the data of sufficient quality to warrant using it for determining the mole fraction-based entropies and enthalpies of vaporization at 25°C, which were then converted to molarity-based quantities
    • Polak J., Lu B.C.-Y. Mutual solubilities of hydrocarbons and water at 25°C. Can. J. Chem. 51:1973;4018-4023 The solubilities of water in various organic solvents were measured at only two temperatures, 0 and 25°C, but we considered the data of sufficient quality to warrant using it for determining the mole fraction-based entropies and enthalpies of vaporization at 25°C, which were then converted to molarity-based quantities.
    • (1973) Can. J. Chem. , vol.51 , pp. 4018-4023
    • Polak, J.1    Lu, B.C.-Y.2
  • 37
    • 55549083907 scopus 로고
    • Determination of the solubility of water in some organic liquids by means of tritium
    • J.R. Jones, C.B. Monk, 1963. Determination of the solubility of water in some organic liquids by means of tritium. J. Chem. Soc. A. (1963) 2633-2635.
    • (1963) J. Chem. Soc. A. , Issue.1963 , pp. 2633-2635
    • Jones, J.R.1    Monk, C.B.2
  • 38
    • 0001645389 scopus 로고
    • Solubility of water in benzene
    • Karlsson R. Solubility of water in benzene. J. Chem. Eng. Data. 18:(3):1973;290-292.
    • (1973) J. Chem. Eng. Data , vol.18 , Issue.3 , pp. 290-292
    • Karlsson, R.1
  • 39
    • 0002234940 scopus 로고
    • 2O in carbon tetrachloride, toluene, and cyclohexane at various temperatures
    • While it met our criteria for inclusion, the result for water in cyclohexane was rejected because it fell so far above every other point we obtained for any solvent, and was therefore considered an outlier
    • 2O in carbon tetrachloride, toluene, and cyclohexane at various temperatures. J. Chem. Eng. Data. 17:(1):1972;66-68 While it met our criteria for inclusion, the result for water in cyclohexane was rejected because it fell so far above every other point we obtained for any solvent, and was therefore considered an outlier.
    • (1972) J. Chem. Eng. Data , vol.17 , Issue.1 , pp. 66-68
    • Glasoe, P.K.1    Schultz, S.D.2
  • 41
    • 0020843612 scopus 로고
    • High-temperature mutual solubilities of hydrocarbons and water, Part I
    • Tsonopoulos C., Wilson G.M. High-temperature mutual solubilities of hydrocarbons and water, Part I. Am. Inst. Chem. Eng. J. 29:(6):1983;990-999.
    • (1983) Am. Inst. Chem. Eng. J. , vol.29 , Issue.6 , pp. 990-999
    • Tsonopoulos, C.1    Wilson, G.M.2
  • 42
  • 43
    • 0001373127 scopus 로고
    • Enthalpies of solution of water in benzene and in some alkanes
    • Nilsson S.-O. Enthalpies of solution of water in benzene and in some alkanes. J. Chem. Thermodyn. 18:1986;877-884.
    • (1986) J. Chem. Thermodyn. , vol.18 , pp. 877-884
    • Nilsson, S.-O.1
  • 44
    • 0001504747 scopus 로고
    • Direct calorimetric measurement of the heats of solution of some liquid hydrocarbons in water
    • Reid D.S., Quickenden M.A.J., Franks F. Direct calorimetric measurement of the heats of solution of some liquid hydrocarbons in water. Nature. 224:1969;1293-1294.
    • (1969) Nature , vol.224 , pp. 1293-1294
    • Reid, D.S.1    Quickenden, M.A.J.2    Franks, F.3
  • 45
    • 0000995152 scopus 로고
    • Alcohol association studies, 3: Vapor pressure measurements for the ethanol-n-hexadecane systems
    • Tucker E.E., Christian S.D. Alcohol association studies, 3: vapor pressure measurements for the ethanol-n-hexadecane systems. J. Phys. Chem. 81:(13):1977;1295-1299.
    • (1977) J. Phys. Chem. , vol.81 , Issue.13 , pp. 1295-1299
    • Tucker, E.E.1    Christian, S.D.2
  • 46
    • 0000238697 scopus 로고
    • The solubility of water in low-dielectric solvents
    • Kirchnerova J., Cave G.C. The solubility of water in low-dielectric solvents. Can. J. Chem. 54:1976;3909-3916.
    • (1976) Can. J. Chem. , vol.54 , pp. 3909-3916
    • Kirchnerova, J.1    Cave, G.C.2
  • 47
    • 0000501295 scopus 로고
    • Temperature dependence of the excess thermodynamic properties of ethanol-methylcyclohexane and ethanol-toluene systems
    • Hwa S.C.P., Ziegler W.T. Temperature dependence of the excess thermodynamic properties of ethanol-methylcyclohexane and ethanol-toluene systems. J. Phys. Chem. 70:(8):1966;2572-2593.
    • (1966) J. Phys. Chem. , vol.70 , Issue.8 , pp. 2572-2593
    • Hwa, S.C.P.1    Ziegler, W.T.2
  • 49
    • 0034620769 scopus 로고    scopus 로고
    • Dissolution and self-assembly: The solvophobic/hydrophobic effect
    • Marmur A. Dissolution and self-assembly: the solvophobic/hydrophobic effect. J. Am. Chem. Soc. 122:2000;2120-2121.
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 2120-2121
    • Marmur, A.1
  • 50
    • 0242339189 scopus 로고
    • Thermodynamic properties: Water in crystalline hydrates and aqueous solutions of simple non-electrolytes
    • F. Franks. New York: Plenum Press. p. 372
    • Franks F., Reid D.S. Thermodynamic properties: water in crystalline hydrates and aqueous solutions of simple non-electrolytes. Franks F. Water: A Comprehensive Treatise, vol. 2. 1973;Plenum Press, New York. p. 372.
    • (1973) Water: A Comprehensive Treatise, vol. 2
    • Franks, F.1    Reid, D.S.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.