Thiocarbyl ligands via elimination of pentafluorobenzene at a diiron centre: Crystal structures of [Fe2(CO)4 {μ-SC(Ph)=CH}(μ-dppm)] and [Fe2(CO)4 {μ-SCH=C(Ph)C(O)}(μ-dppm)]

Journal of Organometallic Chemistry

Volumn 672, Issue 1-2, 2003, Pages 22-28

  Hogarth, Graeme ^a   O'Brien, Matthew ^a   Tocher, Derek A ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

Iron; Pentafluorophenylthiol; Thioalkyne; Thiocarbonyl

Indexed keywords

ALKENYL GROUP; ALKYNE DERIVATIVE; BENZENE DERIVATIVE; BIPHENYL; CARBONYL DERIVATIVE; HYDROCARBON; IRON COMPLEX; LIGAND; METHANE; PHOSPHINE DERIVATIVE; THIOL DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CIS TRANS ISOMERISM; COMPLEX FORMATION; CONTROLLED STUDY; CRYSTAL STRUCTURE; ELECTRON; ELIMINATION REACTION; HIGH TEMPERATURE; NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; TEMPERATURE MEASUREMENT; X RAY CRYSTALLOGRAPHY;

EID: 0037437258     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(03)00135-9     Document Type: Article

References (28)

1. King R.B. Treichel P.M. Stone F.G.A. J. Am. Chem. Soc. 83 1961 3600
2. G. Hogarth, M.H. Lavender, J. Chem. Soc. Dalton Trans. (1994) 3389.
3. Hogarth G. Lavender M.H. Shukri K. J. Organomet. Chem. 527 1997 247
4. Hogarth G. Shukri K. Doherty S. Carty A.J. Enright G.D. Inorg. Chim. Acta 291 1998 178
5. M.K. Anwar, G. Hogarth, O.S. Senturk, W. Clegg, S. Doherty, M.R.J. Elsegood, J. Chem. Soc. Dalton Trans. (2001) 341.
6. S. Doherty, G. Hogarth, Chem. Commun. (1998) 1815.
7. Seyferth D. Hoke J.B. Womak G.B. Organometallics 9 1990 2662
8. Seyferth D. Archer C.M. Ruschke D.P. Cowie M. Hilts R.W. Organometallics 10 1991 3363
9. Seyferth D. Hoke J.B. Dewan J.C. Hofmann P. Schnellbach M. Organometallics 13 1994 3452
10. Seyferth D. Womack G.B. Song L.-C. Cowie M. Hames B.W. Organometallics 2 1983 928
11. Seyferth D. Womack G.B. Dewan J.C. Organometallics 4 1985 398
12. Seyferth D. Anderson L.L. Villafane F. Cowie M. Hilts R.W. Organometallics 11 1992 3262
13. J. Ros, J.M. Vinas, R. Mathieu, X. Solans, M. Font-Bardia, J. Chem. Soc. Dalton Trans. (1988) 281.
14. Song L.-C. Hu Q.-M. Zhou Y.-Y. Liu L. J. Struct. Chem. 8 1989 197
15. Ibbotson A. Reduto dos Reis A.C. .Saberi S.P. Slawin A.M.Z. Thomas S.E. Tustin G.J. Williams D.J. J. Chem. Soc. Perkin Trans. 1 1992 1251
16. Song L.-C. Hu Q.-M. Zhou Z.-Y. Hu G.-Z. Chem. J. Chin. Univ. 12 1991 471
17. Yao X.-K. Wang R.-J. Wang H.-G. Song L.-C. Hu Q.-M. Wang J.-T. Acta. Crystallogr. Sect. C 45 1989 575
18. Fassler T. Huttner G. J. Organomet. Chem. 376 1989 367
19. G. Hogarth, M. O'Brien, Unpublished results.
20. Schrauzer G.N. Rabinowitz H.N. Frank J.K. Paul I.C. J. Am. Chem. Soc. 92 1970 212
21. Schrauzer G.N. Kisch H. J. Am. Chem. Soc. 95 1973 2501
22. Rumin R. Paétillon F.Y. Henderson A.H. Manojlovic-Muir L. Muir K.W. J. Organomet. Chem. 336 1987 C50
23. Rumin R. Pétillon F.Y. Manojlovic-Muir L. Muir K.W. Organometallics 9 1990 944
24. Knoll K. Fassler T. Huttner G. J. Organomet. Chem. 332 1987 309
25. Hickey J.P. Huffman J.C. Todd L.J. Inorg. Chim. Acta 28 1978 77
26. Robin F. Rumin R. Talarmin J. Pétillon F.Y. Muir K.W. Organometallics 12 1993 365
27. Fassler Th. Huttner G. Gunauer D. Fiedler S. Eber B. J. Organomet. Chem. 381 1990 409
28. Doherty S. Hogarth G. Inorg. Chem. Commun. 1 1998 257