Macrocycle synthesis by olefin metathesis on a nanosized, shape-persistent tricationic platinum template

Angewandte Chemie - International Edition

Volumn 42, Issue 2, 2003, Pages 228-230

  Chuchuryukin, Aleksey V ^a   Dijkstra, Harm P ^a   Suijkerbuijk, Bart M J M ^a   Klein Gebbink, Robertus J M ^a   Van Klink, Gerard P M ^a   Mills, Allison M ^b   Spek, Anthony L ^b   Van Koten, Gerard ^a  

^a UTRECHT UNIVERSITY   (Netherlands)

^b UTRECHT UNIVERSITY   (Netherlands)

Author keywords

Macrocyclic ligands; Metathesis; N ligands; Platinum; Template synthesis

Indexed keywords

BENZENE; CHLORINE; NANOSTRUCTURED MATERIALS; PLATINUM;

METATHESIS REACTION;

OLEFINS;

ALKENE; CHLORIDE; MACROCYCLIC COMPOUND; PLATINUM DERIVATIVE;

ARTICLE; NANOPARTICLE; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; RING CLOSING METATHESIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0037434126     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200390086     Document Type: Article

References (21)

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9. For general references on templated synthesis see a) N. V. Gerbeleu, V. B. Arion, J. Burgess, Template Synthesis of Macrocyclic Compounds, Wiley-VCH, Weinheim, 1999; b) F. Diederich, P. J. Stang, Templated Organic Synthesis, Wiley-VCH, Weinheim, 1999.
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18. NMR spectroscopic, mass spectrometric and elemental analysis data are available as Supporting Information.
19. 2[11a] as hydrogenation catalyst or of a nitrogencontaining base as inhibitor for the side reaction[11b] might increase the yield of 6b. a) H. Pettersson-Fasth, S. W. Riesinger, J. E. Bäckvall, J. Org. Chem. 1995, 60, 6091-6096; b) H. Sajiki, K. Hirota, Tetrahedron 1998, 54, 13981-13996.
20. 2[11a] as hydrogenation catalyst or of a nitrogencontaining base as inhibitor for the side reaction[11b] might increase the yield of 6b. a) H. Pettersson-Fasth, S. W. Riesinger, J. E. Bäckvall, J. Org. Chem. 1995, 60, 6091-6096; b) H. Sajiki, K. Hirota, Tetrahedron 1998, 54, 13981-13996.
21. -3. CCDC185367 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre. 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).