Synthesis and characterization of transition-metal zintl phases: K10NblnAs6 and K9Nb2As6

Inorganic Chemistry

Volumn 42, Issue 3, 2003, Pages 904-907

  Gascoin, Franck ^a   Sevov, Slavi C ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIMER; TRANSITION ELEMENT;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; MAGNETISM; SYNTHESIS; TEMPERATURE; X RAY DIFFRACTION;

EID: 0037429199     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020557a     Document Type: Article

References (12)

1. Gascoin, F.; Sevov S. C. Inorg. Chem. 2002, 41, 5920.
2. Demadis, K. D.; Hartshorn, C. M.; Meyer, T. J. Chem. Rev. 2001, 101, 2655.
3. (a) Kauzlarich, S. M. In Chemistry and Bonding of Zintl Phases and Ions; Kauzlarich, S. M., Ed.; VCH Publishers: New York, 1996; p 245.
4. (b) Hyungrak, K.; Condron, C. L.; Holm, A. P.; Kauzlarich, S. M. J. Am. Chem. Soc. 2000, 122, 10720.
5. Del Castillo, J.; Webb, D. J.; Kauzlarich, S. M.; Kuromoto, T. Y. Phys. Rev. B 1993, 47, 4849. Rehr, A.; Kuromoto, T. Y.; Kauzlarich, S. M.; Del Castillo, J.; Webb, D. J. Chem. Mater. 1994, 6, 93. Webb, D. J.; Cohen, R.; Klavins, P.; Shelton, R. N.; Chan, J. Y.; Kauzlarich, S. M. J. Appl. Phys. 1998, 83, 7192.
6. Del Castillo, J.; Webb, D. J.; Kauzlarich, S. M.; Kuromoto, T. Y. Phys. Rev. B 1993, 47, 4849. Rehr, A.; Kuromoto, T. Y.; Kauzlarich, S. M.; Del Castillo, J.; Webb, D. J. Chem. Mater. 1994, 6, 93. Webb, D. J.; Cohen, R.; Klavins, P.; Shelton, R. N.; Chan, J. Y.; Kauzlarich, S. M. J. Appl. Phys. 1998, 83, 7192.
7. Del Castillo, J.; Webb, D. J.; Kauzlarich, S. M.; Kuromoto, T. Y. Phys. Rev. B 1993, 47, 4849. Rehr, A.; Kuromoto, T. Y.; Kauzlarich, S. M.; Del Castillo, J.; Webb, D. J. Chem. Mater. 1994, 6, 93. Webb, D. J.; Cohen, R.; Klavins, P.; Shelton, R. N.; Chan, J. Y.; Kauzlarich, S. M. J. Appl. Phys. 1998, 83, 7192.
8. (a) Gascoin, F.; Sevov, S. C. Inorg. Chem. 2002, 41, 2820.
9. (b) Gascoin, F.; Sevov, S. C. Angew. Chem., Int. Ed. 2002, 41, 1232.
10. (c) Nuss, J.; Cardoso Gil, R. H.; Hönle, W.; Peters, K.; von Schnering, H. G. Z. Anorg. Allg. Chem. 1996, 622, 1854.
11. 6] in a ratio 1:1:1. Apparently, the structure is intrinsically disordered, and more studies are needed in order to confirm the results.
12. Gascoin, F.; Sevov, S. C. Inorg. Chem. 2002, 41, 2292.