Kinetics and mechanism of ligand substitution in β-diketone complexes of iron(III). Solvolysis controlling the substitution process in alcohol media

Inorganica Chimica Acta

Volumn 342, Issue , 2003, Pages 97-106

  Gumbel, Gerhard ^a   Elias, Horst ^a  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

Iron(III) complexes; Kinetics; Ligand substitution; Mechanism; diketones

Indexed keywords

DISSOCIATION; ENZYME KINETICS; KETONES; KINETICS; LIGANDS; MECHANISMS; RATE CONSTANTS; SOLVENTS; SPECTROPHOTOMETRY;

BINUCLEAR COMPLEXES; DIKETONES; FIRST-ORDER RATE CONSTANTS; INTERMEDIATE COMPLEX; KINETICS AND MECHANISM; LIGAND SUBSTITUTION; SOLVENT POLARITY PARAMETER; STOPPED-FLOW SPECTROPHOTOMETRY;

IRON COMPOUNDS;

1 (2 THIENYL) 4,4,4 TRIFLUOROBUTANE 1,3 DIONE; 1, PHENYLBUTANE 1,3 DIONE; 1,3 DIKETONE; 1,3 DIPHENYLPROPANE 2,3 DIONE; 2,2,6,6 TETRAMETHYLHEPTANE 3,5 DIONE; 2,6 DIMETHYLHEPTANE 3,5 DIONE; 8 QUINOLINOL; ALCOHOL; ANION; BETA DIKETONE PENTANE 2,4 DIONE; IRON; IRON COMPLEX; KETONE DERIVATIVE; TRIS(BETA DIKETONE IRON); UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; KINETICS; SOLVOLYSIS; SPECTROPHOTOMETRY;

EID: 0037427928     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01143-X     Document Type: Article

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