Mono- and di-functional aromatic amines with p-alkoxy substituents as novel arylimido ligands for the hexamolybdate ion

Inorganica Chimica Acta

Volumn 342, Issue , 2003, Pages 37-47

  Roesner, R A ^a   McGrath, S C ^a   Brockman, J T ^a   Moll, J D ^a   West, D X ^b   Swearingen, J K ^b   Castineiras, A ^c  

^a ILLINOIS WESLEYAN UNIVERSITY   (United States)

^b ILLINOIS STATE UNIVERSITY   (United States)

^c UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

Author keywords

Crystal structures; Hexamolybdate ion; Imido ligands; Mass spectroscopy; Polyoxoanions; Polyoxometalate

Indexed keywords

AMINES; AROMATIC COMPOUNDS; BOND LENGTH; CRYSTAL STRUCTURE; IONS; LIGANDS; MASS SPECTROMETRY; POLYOXOMETALATES; SPECTROSCOPIC ANALYSIS;

ALKOXY SUBSTITUENTS; AROMATIC AMINES; DIETHYL ETHERS; IMIDO LIGAND; MASS SPECTROSCOPY; POLYOXOANIONS; POLYOXOMETALATE; TETRABUTYLAMMONIUM SALTS;

X RAY CRYSTALLOGRAPHY;

ACETONITRILE; AROMATIC AMINE; ETHER; HEXAMOLYBDATE; HISTAMINE; ION; LIGAND; MOLYBDIC ACID; NITROMETHANE; PYRIDINE; TETRABUTYLAMMONIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTALLIZATION; INFRARED RADIATION; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

EID: 0037427901     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01075-7     Document Type: Article

References (48)

1. (a) Pope M.T., Müller A. Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity. Kluwer, Dordrecht, 1994
2. (b) C.L. Hill (Guest Ed.), Chem. Rev. 98 (1998) 1.
3. (c) Pope M.T., Müller A. Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications. Kluwer, Dordrecht. 2001
4. Hainfeld J.F., Foley C.J., Maelia L.E., Lipka J.J. J. Histochem. Cytochem. 38:1990;1787.
5. Keana J.F.W., Ogan M.D., Lü Y. J. Am. Chem. Soc. 107:1985;6714.
6. Keana J.F.W., Ogan M.D., Lü Y., Beer M., Varkey J. J. Am. Chem. Soc. 108:1986;7957.
7. Zhang S.-W., Wei Y.-G., Yu Q., Shao M.-C., Tang Y.-Q. J. Am. Chem. Soc. 119:1997;6640.
8. Moore A.R., Kwen H., Beatty A.M., Maatta E.A. Chem. Commun. 2000;1793.
9. Mayer C.R., Thouvenot R., Lalot T. Chem. Mater. 12:2000;257.
10. Zeng H., Newkome G.R., Hill C.L. Angew. Chem., Int. Ed. Engl. 39:2000;1771.
11. Strong J.B., Yap G.P.A., Ostrander R., Liable-Sands L.M., Rheingold A.L., Thouvenot R., Gouzerh P., Maatta E.A. J. Am. Chem. Soc. 122:2000;639.
12. Clegg W., Errington R.J., Fraser K.A., Holmes S.A., Schäfer A. J. Chem. Soc., Chem. Commun. 1995;455.
13. Wei Y., Xu B., Barnes C.L., Peng Z. J. Am. Chem. Soc. 123:2001;4083.
14. Proust A., Thouvenot R., Chaussade M., Robert F., Gouzerh P. Inorg. Chim. Acta. 224:1994;81.
15. Du Y., Rheingold A.L., Maatta E.A. J. Am. Chem. Soc. 114:1992;345.
16. Strong J.B., Ostrander R., Rheingold A.L., Maatta E.A. J. Am. Chem. Soc. 116:1994;3601.
17. Clegg W.C., Errington R.J., Fraser K.A., Holms S.A., Schäfer A. J. Chem. Soc., Chem. Commun. 1995;455.
18. Stark J.L., Rheingold A.L., Maatta E.A. J. Chem. Soc., Chem. Commun. 1995;1165.
19. A.R. Moore, Ph.D. Dissertation, Kansas State University, Mahattan, KS, 1998.
20. Moore A.R., Kwen H., Beatty A.M., Maatta E.A. Chem. Commun. 2000;1793.
21. Stark J.L., Young V.G. Jr., Maatta E.A. Angew. Chem., Int. Ed. Engl. 34:1995;2547.
22. Xu B., Wei Y., Barnes C.L., Peng Z. Angew. Chem., Int. Ed. Engl. 40:2001;2290.
23. Hogarth G., Humphrey D.G., Kaltsoyannis N., Kim W.-S., Lee M., Norman T., Redmond S.P. J. Chem. Soc., Dalton Trans. 1999;2705.
24. Wei Y., Xu B., Barnes C.L., Peng Z. J. Am. Chem. Soc. 123:2001;4083.
25. Hur N.H., Klemperer W.G., Wang R.-C. Inorg. Synth. 27:1990;77.
26. Che M., Fournier M., Launay J.P. J. Chem. Phys. 71:1979;1954.
27. Bartulín J., Ramos M.L., Rivas B.L. Polym. Bull. 15:1986;405.
28. Griffin A.C., Britt T.R., Hung R.S.L., Steele M. Mol. Cryst. Liq. Cryst. 105:1984;305.
29. B.V. Nonius, CAD4-Express Software, Ver. 5.1/1.2., Enraf-Nonius, Delft, The Netherlands, 1994.
30. M. Kretschmar, GENHKL Program for the Reduction of CAD4 Diffractometer Data, University of Tübingen, Tübingen, Germany, 1997.
31. North A.C.T., Phillips D.C., Mathews F.S. Acta Crystallogr., A. 24:1968;351.
32. Sheldrick G.M. Acta Crystallogr. A. 46:1990;467.
33. G.M. Sheldrick, SHELXL-97 Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.
34. International Tables for Crystallography, vol. C, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1995.
35. A.L. Spek, PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands, 1998.
36. Emsley J. The Elements. 2nd ed. 1991;119 Clarendon Press, Oxford.
37. Bottomley F., Chen J. Organometallics. 11:1992;3404.
38. Kwen H., Young V.G. Jr., Maatta E.A. Angew. Chem., Int. Ed. Engl. 38:1999;1145.
39. Hsieh T.-C., Zubieta J.A. Polyhedron. 5:1986;1655.
40. Bank S., Liu S., Shaikh S.N., Sun X., Zubieta J., Ellis P.D. Inorg. Chem. 27:1988;3535.
41. Proust A., Thouvenot R., Robert F., Gouzerh P. Inorg. Chem. 32:1993;5299.
42. Stark J.L., Young V.G. Jr., Maatta E.A. Angew. Chem., Int. Ed. Engl. 34:1995;5299.
43. Kang H., Zubieta J. J. Chem. Soc., Chem. Commun. 1988;1192.
44. Proust A., Thouvenot R., Herson P. J. Chem. Soc., Dalton Trans. 1999;51.
45. Che T.M., Day V.W., Francesconi L.C., Fredrich M.F., Klemperer W.G. Inorg. Chem. 24:1985;4055.
46. Fuchs J., Freiwald W., Hartl H. Acta Crystallogr. B. 34:1978;1764.
47. 2- [5a] and those positions were locked for subsequent minimizations. The Mo=N-C bond angles were fixed at 170° while the remainder of the organic ligand was geometrically unconstrained. The structures converged normally for n≥8. The eight-membered methylene strap had C-C single bond lengths of 1.54 Å and C-C-C bond angles ranging from 111.68 to 114.64°. While these angles are slightly greater than the tetrahedral angle, comparable bond angles have been observed in the polymethylene straps of other constrained, macrocyclic systems [33].
48. M.W. Glogowski, Ph.D. Dissertation, The Ohio State University, Columbus, OH, 1988.