Kinetic results implicating a polar radical reaction pathway in the rearrangement catalyzed by α-methyleneglutarate mutase

Journal of the American Chemical Society

Volumn 125, Issue 14, 2003, Pages 4080-4086

  Newcomb, Martin ^a   Miranda, Neil ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

POLAR RADICAL REACTIONS;

CARBOXYLIC ACIDS; CATALYSIS; ESTERS; FREE RADICALS; PHOTOLYSIS; POLARIZATION; RATE CONSTANTS;

ENZYME KINETICS;

MUTASE; RADICAL;

ANALYTIC METHOD; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CYCLIZATION; DERIVATIZATION; ENZYME MECHANISM; GENE REARRANGEMENT; HYDROGEN BOND; PHOTOLYSIS; RING OPENING; THERMODYNAMICS;

CATALYSIS; CYCLIZATION; FREE RADICALS; GLUTARATES; INTRAMOLECULAR TRANSFERASES; KINETICS; PHOTOLYSIS; THERMODYNAMICS;

EID: 0037427237     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028686d     Document Type: Article

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