Syntheses and structural characterizations of endo-η1-, exo-η1-, η4-, η5-, and η6-metallaphosphamonocarbaborane complexes derived from a versatile new polyborane ligand: exo-6-R-arachno-6,7-PCB8H12

Journal of the American Chemical Society

Volumn 125, Issue 1, 2003, Pages 212-220

  Kadlecek, Daniel E ^a   Shedlow, Alexandra M ^a   Kang, Sang Ook ^b   Carroll, Patrick J ^a   Sneddon, Larry G ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

^b Korea University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLOGRAPHY; ISOMERS; METHANOL; NEGATIVE IONS; PHOSPHATES; STRUCTURAL ANALYSIS; THERMODYNAMICS;

DEPROTONATION;

SYNTHESIS (CHEMICAL);

BORANE DERIVATIVE; FERROCENE DERIVATIVE; IRON; MANGANESE DERIVATIVE; METAL COMPLEX; PLATINUM DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BINDING; COMPLEX FORMATION; CRYSTAL STRUCTURE; ISOMER; PHOTOLYSIS; PROTON TRANSPORT; SYNTHESIS; THERMODYNAMICS;

EID: 0037425519     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja020945b     Document Type: Article

References (32)

1. University of Pennsylvania
2. Korea University
3. Shedlow, A. M.; Kadlecek, D. E.; Rathmill, S.; Clapper, J. C.; Carroll, P.; Sneddon, L. G. J. Am. Chem. Soc. 2002, 124, 200-211.
4. Shriver, D. F.; Drezdzon, M. A. Manipulation of Air-Sensitive Compounds, 2nd Ed.; Wiley: New York, 1986.
5. Evans. D. F. J. Chem. Soc. 1959, 2003-2005.
6. (b) Carlin, R. L. J. Chem. Educ. 1966, 43. 521-525.
7. (c) Sur, S. K. J. Magn. Reson. 1989, 82, 169-173.
8. The coupling constant could not be accurately measured.
9. bioteX: A Suite of Programs for the Collection, Reduction, and Interpretation of Imaging Plate Data, Molecular Structure Corporation, 1995.
10. teXsan: Crystal Structure Analysis Package. Molecular Structure Corporation. 1985 & 1992.
11. REQAB4: Jacobsen. R. A. Private Communication, 1994.
12. SIR92: Altomare, A.; Burla, M. C.; Camalli, M.: Cascarano, M.; Giacovazzo, C.; Guagliardi, A.; Polidoro, G. J. Appl. Cryst. 1994, 27, 435.
13. SQUEEZE: Sluis, P. v. d.; Spek, A. L. Acta Cryst. 1990, A46, 194.
14. Sheldrick, G. M. SHELXL-93: Program for the Refinement of Crystal Structures; University of Göttingen: Göttingen, Germany, 1993.
15. As given in the Experimental Section, the 160.5 MHz 11B NMR spectrum of 2 resolves into seven peaks of relative intensities 1:1:1:1:2:1:1.
16. Hoic, D. A.; Davis, W. M.; Fu, G. C. J. Am. Chem. Soc. 1996, 118, 8176-8177.
17. Burckett-St. Laurent, J. C. T. R.; Haines, R. J.; Nolte, C. R.; Steen, N. D. C. T. Inorg. Chem. 1980, 19, 577-587.
18. Lee, S. S.; Knobler, C. B.; Hawthorne, M. F. Organometallics 1991, 10, 1054-1062.
19. (a) Wade, K. Adv. Inorg. Chem. Radiochem. 1976, 18, 1-66.
20. (b) Williams, R. E. Adv. Inorg. Chem. Radiochem. 1976, 18, 67-142.
21. (c) Williams, R. E. Chem. Rev. 1992, 92, 117-201.
22. (d) Williams, R. E. In Electron Deficient Boron and Carbon Clusters; Olah, G. A., Wade, K., Williams, R. E., Eds.: Wiley: New York, 1991.
23. Plumb, C. A.; Carroll, P. J.; Sneddon, L. G. Orgatlometallics 1992, 11, 1665-1671.
24. Bausch, J. W.; Rizzo, R. C.; Sneddon, L. G.; Wille, A. E.; Williams, R. E. Inorg. Chem. 1996, 35, 131-135.
25. Barnum, B. A.; Carroll, P. J.; Sneddon, L. G. Inorg. Chem. 1997, 36, 1327-1337.
26. See, for example: Plumb, C. A.; Carroll, P. J.; Sneddon, L. G. Organometallics 1992, 11, 1672-1680 and references therein.
27. Callahan, K. P.; Evans, W. J.; Lo, F. Y.; Strouse, C. E.; Hawthorne, M. F. J. Am. Chem. Soc. 1975, 97, 296-302.
28. Greene, P. T.; Bryan, R. F. Inorg. Chem. 1970, 9, 1464-1471.
29. Grimes, R. N.; Maynard, R. B.; Sinn, E.; Brewer, G. A.; Long, G. J. J. Am. Chem. Soc. 1982, 104, 5987-5992.
30. Anderson, G. K.; Clark, H. C.; Davies, J. A.; Ferguson, G.; Parvez, M. J. Cryst. Spectrosc. Res. 1982, 12, 449-458.
31. Johansson, M. H.; Otto, S. Acta Crystallogr. 2000, C56, e12.
32. Barnum, B. A.; Carroll, P. J.; Sneddon, L. G. Organometallics 1996, 15, 645-654.