Modelling nucleophilic substitution at silicon using solution 19 F-NMR chemical shift, 1 J Si-F and 2 J C-F coupling constant data of pentacoordinate silicon compounds. Correlation with other magnetic nuclei and X-ray structures

Journal of Organometallic Chemistry

Volumn 669, Issue 1-2, 2003, Pages 154-163

  Bassindale, Alan R ^a   Baukov, Yuri I ^b   Borbaruah, Moheswar ^a   Glynn, Simon J ^a   Negrebetsky, Vadim V ^b   Parker, David J ^a   Taylor, Peter G ^a   Turtle, Robert ^a  

^a OPEN UNIVERSITY   (United Kingdom)

^b Dept of General/Bioorganic Chem ^*  (Russian Federation)

Author keywords

Coupling constant; Fluorine NMR; Nucleophilic substitution; Pentacoordinate; Silicon; Structural correlation; X ray study

Indexed keywords

CARBON; COORDINATION COMPOUND; FLUORIDE; FLUORINE; SILICON; SILICON DERIVATIVE;

CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL PROCEDURES; CHEMICAL STRUCTURE; CORRELATION ANALYSIS; DATA ANALYSIS; MOLECULAR MODEL; NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REVIEW; SUBSTITUTION REACTION; VALIDATION PROCESS; X RAY CRYSTALLOGRAPHY;

EID: 0037417097     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(03)00009-3     Document Type: Article

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