Three-phase catalytic hydrogenation of α-methylstyrene in supercritical carbon dioxide

Journal of Supercritical Fluids

Volumn 25, Issue 2, 2003, Pages 155-164

  Phiong, Hon Sang ^a   Lucien, Frank P ^a   Adesina, Adesoji A ^a  

^a UNIVERSITY OF NEW SOUTH WALES   (Australia)

Author keywords

Methylstyrene; Carbon dioxide; Catalytic hydrogenation

Indexed keywords

ALPHA METHYLSTYRENE; CARBON DIOXIDE; PALLADIUM; STYRENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; HYDROGENATION; LIQUID; MATHEMATICAL MODEL; PRESSURE; SOLUBILITY; SUPERCRITICAL FLUID; VOLUMETRY;

EID: 0037368150     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0896-8446(02)00092-X     Document Type: Article

References (15)

1. P.G. Jessop, W. Leitner, Chemical Synthesis in Supercritical Fluids, Wiley-VCH, Weinheim, 1999.
2. P.G. Jessop, T. Ikariya, R. Noyori, Homogeneous catalysis in supercritical fluids, Chem. Rev. 99 (1999) 475.
3. A. Baiker, Supercritical fluids in heterogeneous catalysis, Chem. Rev. 99 (1999) 453.
4. 2, Chem. Eng. Sci. 52 (1997) 4163.
5. B. Subramaniam, M.A. McHugh, Reactions in supercritical fluids - a review, Ind. Eng. Chem. Process. Des. Dev. 25 (1986) 1.
6. P.A. Ramachandran, R.V. Chaudhari, Three-Phase Catalytic Reactors, Gordon and Breach, New York, 1983.
7. 2, Catalysis Today 48 (1999) 337.
8. S. Ohe, Vapour-Liquid Equilibrium Data at High Pressure, Kodansha, Tokyo, 1990.
9. P.M. Gallagher, M.P. Coffey, V.J. Krukonis, N. Klasutis, Gas antisolvent recrystallization: new process to recrystallize compounds insoluble in supercritical fluids, in: K.P. Johnston, J.M.L. Penninger (Eds.), Supercritical Fluid Science and Technology, American Chemical Society, Washington, DC, 1989, p. 334.
10. A. Kordikowski, A.P. Schenk, R.M. Van Nielen, C.J. Peters, Volume expansions and vapor-liquid equilibria of binary mixtures of a variety of polar solvents and certain near-critical solvents, J. Supercrit. Fluids 8 (1995) 205.
11. E. Reverchon, Supercritical antisolvent precipitation of micro- and nano-particles, J. Supercrit. Fluids 15 (1999) 1.
12. F. Turco, R.R. Hudgins, P.L. Silveston, S. Sicardi, L. Manna, M. Banchero, Investigation of periodic operation of a trickle-bed reactor, Chem. Eng. Sci. 56 (2001) 1429.
13. A.T. Castellari, P.M. Haure, Experimental study of the periodic operation of a trickle-bed reactor, AIChE J. 41 (1995) 1593.
14. H-S. Phiong, F.P. Lucien, Volumetric expansion and vapour-liquid equilibria of α-methylstyrene and cumene with carbon dioxide at elevated pressure, J. Supercrit. Fluids., in this issue.
15. 2: kinetic measurements in a gradientless internal-recycle reactor, Ind. Eng. Chem. Res. 36 (1997) 2626.