Formation behavior of PCDD/FS in PVC pyrolysis with copper oxide

Chemosphere

Volumn 50, Issue 9, 2003, Pages 1235-1242

  Shibata, Etsuro ^a   Yamamoto, Satoru ^a   Kasai, Eiki ^a   Nakamura, Takashi ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

CuO; Formation; PCDD Fs; PVC; Pyrolysis; Thermodynamic calculation

Indexed keywords

COPPER OXIDES; DECOMPOSITION; PYROLYSIS; THERMODYNAMICS;

DECOMPOSITION BEHAVIOR;

POLYVINYL CHLORIDES;

COPPER DERIVATIVE; COPPER OXIDE; POLYCHLORINATED DIBENZODIOXIN; POLYCHLORINATED DIBENZOFURAN; POLYVINYLCHLORIDE; UNCLASSIFIED DRUG;

PYROLYSIS;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; CHEMICAL REACTION; DECHLORINATION; DECOMPOSITION; PYROLYSIS; REACTION ANALYSIS; THERMODYNAMICS;

BENZOFURANS; COPPER; INCINERATION; POLYVINYL CHLORIDE; TEMPERATURE; TETRACHLORODIBENZODIOXIN; THERMODYNAMICS; TIME FACTORS;

EID: 0037366126     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0045-6535(02)00580-5     Document Type: Article

References (22)

1. Addink, R., Altwicker, E.R., 1998. Role of copper compounds in the de novo synthesis of polychlorinated dibenzo-p-dioxins/dibenzofurans. Environmental Engineering Science 15, 19-27.
2. Addink, R., Olie, K., 1995. Role of oxygen in formation of PCDD/F from carbon on fly ash. Environmental Science and Technology 29, 1586-1590.
3. Addink, R., Drijver, D.J., Olie, K., 1991. Formation of polychlorinated dibenzo-p-dioxins/dibenzofurans in the carbon/fly ash system. Chemosphere 23, 1205-1211.
4. Bockhorn, H., Hornung, A., Hornyng, U., Jakobströer, P., Kraus, M., 1999. Dehydrochlorination of plastic mixtures. Journal of Analytical and Applied Pyrolysis 49, 97-106.
5. Born, J.G.P., Mulder, P., Louw, R., 1993. Fly ash mediated reactions of phenol and monochlorophenols: oxychlorination, deep oxidation, and condensation. Environmental Science and Technology 27, 1849-1863.
6. Fiedler, H., 1998. Thermal formation of PCDD/PCDF: A survey. Environmental Engineering Science 15, 49-58.
7. Froese, K.L., Hutzinger, O., 1996a. Polychlorinated benzene, phenol, dibenzo-p-dioxin, and dibenzofuran in heterogeneous combustion reactions of acetylene. Environmental Science and Technology 30, 998-1008.
8. Froese, K.L., Hutzinger, O., 1996b. Polychlorinated benzene and polychlorinated phenol in heterogeneous combustion reactions of ethylene and ethane. Environmental Science and Technology 30, 1009-1013.
9. F*A*C*T (FACT-Win 3.05), 1999. Facility for the analysis of chemical thermodynamics. CRCT, Pavillon André-Aisenstadt, Suite 6467, 2920 Chemin de la Tour, Montreal, Quebec, Canada.
10. Hagenmaier, H., Brunner, H., Haag, R., 1987. Coppercatalyzed dechlorination/hydrogenation of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and other chlorinated aromatic compounds. Environmental Science and Technology 21, 1085-1088.
11. Halonen, I., Tarhanen, J., Ruokojarvi, P., Tuppurainen, K., Ruuskanen, J., 1995. Effect of catalysts and chlorine source on the formation of organic chlorinated compounds. Chemosphere 30, 1261-1273.
12. Luijk, R., Akkerman, D.M., Slot, P., 1994. Mechanism of formation of polychlorinated dibenzo-p-dioxins and dibenzofurans in the catalyzed combustion of carbon. Environmental Science and Technology 28, 312-321.
13. McNeill, I.C., Memetea, L., Mohammed, H., Fernandes, A.R., Ambidge, P., 1998. Polychlorinated dibenzodioxins and dibenzofurans in PVC pyrolysis. Polymer Degradation and Stability 62, 145-155.
14. Montaudo, G., Puglisi, C., 1991. Evolution of aromatics in the thermal degradation of poly (vinyl chloride): a mechanistic study. Polymer Degradation and Stability 33, 229-262.
15. Olie, K., Vermeulen, P.L., Hutzinger, O., 1977. Chlorodibenzo-p-dioxins and chlorodibenzofurans are trace components of fly ash and flue gas of some municipal waste incinerators in the Netherlands. Chemosphere 6, 445-459.
16. Shibata, E., Yamamoto, S., Koyo, H., Ikeda, T., Kasai, E., Maeda, M., Nakamura, T., 2001. Measurement of thermodynamic functions of solid phase for DD, DF, OCDD and OCDF, and estimation of thermodynamic functions of gas phase for PCDD/Fs using molecular orbital method with density functional theory. Materials Transactions 42, 2531-2536.
17. Stieglitz, L., 1998. Selected topics on the de novo synthesis of PCDD/PCDF on fly ash. Environmental Engineering Science 15, 5-18.
18. Stieglitz, L., Zwick, G., Beck, J., Roth, W., Vogg, H., 1989. On the de novo-synthesis of PCDD/PCDF on fly ash of municipal waste incinerators. Chemosphere 18, 1219-1226.
19. Stieglitz, L., Bautz, H., Zwick, G., Will, R., Schild, D., Römer, J., 1996. On the dual role of metal catalysts in the de-novosynthesis of organochlorine compounds on fly ash from municipal waste incinerators. Organohalogen Compounds 27, 5-9.
20. Vogg, H., Metzger, M., Stieglitz, L., 1987. Recent findings on the decomposition of PCDD/PCDF in municipal waste incineration. Waste Management and Research 5,285-294.
21. Weber, R., Sakurai, T., Hagenmaier, H., 1999. Formation and destruction of PCDD/PCDF during heat treatment of fly ash samples from fluidized bed incinerators. Chemosphere 38, 2633-2642.
22. 4) and polyvinyl chloride under inert atmosphere. Materials Transactions, JIM 41, 1342-1350.