A new synthesis of [26,28-2H6]brassinolide and [26,28-2H6]castasterone via an unusual methyl migration

Journal of Labelled Compounds and Radiopharmaceuticals

Volumn 46, Issue 3, 2003, Pages 231-242

  Kolbe, A ^a   Porzel, A ^a   Schmidt, J ^a   Adam, G ^a  

^a LEIBNIZ INSTITUTE OF PLANT BIOCHEMISTRY   (Germany)

Author keywords

Brassinosteroids; 26,28 2H6 castasterone; 26,28 2H6 brassinolide; 3 2H3 methyl but 1 yne 4,4,4 2H3

Indexed keywords

3-[2H3]METHYL-BUT-1-YNE- [4,4,4-2H3]; BRASSINOLIDE; BRASSINOSTEROID;; BRASSINOSTEROIDS; CASTASTERONE; METHYL MIGRATIONS; SYNTHESISED; TRIMETHYLALUMINUM; [26,28-2H6] CASTASTERONE; [26,28-2H6]BRASSINOLIDE;;

DEUTERIUM;

3 METHYL BUT 1 YNE 4,4,4 H 2; 6,6 ETHYLENEDIOXY 20 FORMYL 2ALPHA,3ALPHA ISOPROPYLIDENEDIOXY 5ALPHA PREGNANE; BRASSINOLIDE 26,28 H 2; BRASSINOSTEROID; CASTASTERONE 26,28 H 2; EPOXIDE; LITHIUM DERIVATIVE; PREGNANE DERIVATIVE; TRIMETHYLALUMINUM N BUTYLLITHIUM; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; DRUG MANUFACTURE; DRUG STRUCTURE; ISOTOPE LABELING; MIGRATION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 0037347994     PISSN: 03624803     EISSN: None     Source Type: Journal    
DOI: 10.1002/jlcr.662     Document Type: Article

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