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0034703389
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Arylglyoxylates via Ishii oxidation of arylacetic acid esters
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33751154737
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2 in the absence of additional metal catalyst or aldehyde co-substrate
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See also ref 15-16
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2 in the absence of additional metal catalyst or aldehyde co-substrate: Y Ishii, K. Nakayama, M. Takeno, S. Sakaguchi, T. lwahama, Y. Nishiyama, J Org. Chem. 1995, 60, 3934-3935. See also ref 15-16.
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17
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0013299744
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note
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[13]
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18
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0013299745
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note
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[7]
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19
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0034613165
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Benzoic acid, formed from benzaldehyde during the co-oxidation, has recently been found to enhance the Co/NHPI-catalyzed alcohol oxidation
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Benzoic acid, formed from benzaldehyde during the co-oxidation, has recently been found to enhance the Co/NHPI-catalyzed alcohol oxidation: T. Iwahama, Y. Yoshino, T. Keitoku, S. Sakaguchi, Y. Ishii, J Org. Chem. 2000, 65, 6502-6507.
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Iwahama, T.1
Yoshino, Y.2
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Ishii, Y.5
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20
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0013262940
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note
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[6]).
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21
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0013250964
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note
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The radical chain character of the reaction is also proven by the fact that no oxidation was observed in the presence of a trace amount of 2,6-di-tert-butyl-4-methylphenol as radical inhibitor.
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24
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0001379685
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The rate of oxidation of an unreactive substrate increases upon addition of a co-substrate that is readily oxidized provided that the rate of termination does not increase on addition of the cosubstrate
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[25]
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[25]
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Walling, C.1
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26
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0013200673
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note
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In accordance with Ishii's observation (ref. 11), phthalimide has been detected as a decomposition product of NHPI. Gradual decomposition of NHPI to inert phthalimide accounts for the high amount of NHPI that is required in NHPI-catalyzed oxidations.
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27
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0013201529
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[25] p. 40
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[25] p. 40.
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-
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28
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0013306188
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note
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2. This could well be the mechanism behind initiation by cobalt, although Co concentrations under Ishii conditions are much larger than under our co-oxidation conditions.
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29
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0013297199
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F. Márta, E. Boga, M. Matók, Discuss. Faraday Soc. 1968, 46, 173-183.
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0013199744
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[2], p. 245
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[2], p. 245.
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33
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0001213674
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0013262135
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Petrov, L.V.1
Solyanikov, V.M.2
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35
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0013250967
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note
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IV is also likely to be induced by perbenzoic acid.
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-
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36
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0001601919
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o = 0.9V] oxidation, see: I. Dellien, F. M. Hall, L. G. Hepler, Chem. Rev. 1976, 76, 283-310.
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(Eds.: J. C. Bailar, A. F. Trotman-Dickenson), Pergamon Press: Oxford
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Rollinson, C.L.1
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42
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0013200158
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note
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To prevent crystallization of benzoic acid in the PhCH supply tube. 10 vol% AcOH was added to the PhCH(O)
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