A laboratory and theoretical study on the uptake of SO2 gas by large and small water drops containing heavy metal ions

Journal of Atmospheric Chemistry

Volumn 44, Issue 2, 2003, Pages 211-223

  Heusel Waltrop, A ^a   Diehl, K ^a   Mitra, S K ^a   Pruppacher, H R ^a  

^a JOHANNES GUTENBERG UNIVERSITY   (Germany)

Author keywords

Catalytic oxidation; Gas uptake; Heavy metal ions; Sulfur dioxide; Sulfuric acid; Water droplets

Indexed keywords

HEAVY METAL; IRON; MANGANESE; METAL ION; SULFUR; SULFUR DIOXIDE; WATER;

ATMOSPHERIC CHEMISTRY; CATALYSIS; DROPLET; GAS EXCHANGE; HEAVY METAL; SULFUR DIOXIDE;

ATMOSPHERE; CATALYSIS; CHEMICAL MODEL; CONTROLLED STUDY; GAS; INTERMETHOD COMPARISON; LIQUID; OXIDATION; PARTICLE SIZE; REVIEW; SUSPENSION; THEORETICAL STUDY; VELOCITY;

EID: 0037303593     PISSN: 01677764     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1022476902546     Document Type: Review

References (26)

1. Barrie, L. A., 1985: Features of the atmospheric cycle of aerosol trace elements and sulfur dioxide revealed by baseline observations in Canada, J. Atmos. Chem. 3, 139-152.
2. Barrie, L. A. and Georgii, H. W., 1976: An experimental investigation of the absorption of sulfur dioxide by water drops containing heavy metal ions, Atmos. Environ. 10, 743-749.
3. Beard, K. V. and Pruppacher, H. R., 1969: A determination of the terminal velocity and drag of small water drops by means of a wind tunnel, J. Atmos. Sci. 26, 1066-1072.
4. Beilke, S., 1970: Laboratory investigations of washout trace gases, Precipitation Scavenging - 1970, U.S. Atomic Energy Commission, Nat. Techn. Info. Service, U.S. Dept. Commerce, Springfield VA, pp. 261-267.
5. Beilke, S. and Georgii, H. W., 1968: Investigation on the incorporation of sulfur dioxide into fog and raindrops, Tellus 20, 435-441.
6. 2 in aqueous systems, Tellus 20, 435-441.
7. 2 oxidation mechanisms: Atmospheric considerations, Acid Precipitation Series 3, Butterworth Publishers, 254 pp.
8. Daum, P. H., Schwartz, S. E., and Newman, L., 1983: Studies of the gas and aqueous phase composition of stratiform clouds, Precipitation Scavenging, Dry Deposition, and Resuspension 1, 31-51.
9. Diehl, K., Vohl, O., Mitra, S. K., and Pruppacher, H. R., 2000: A laboratory and theoretical study on the uptake of sulfur dioxide gas by small water drops containing hydrogen peroxide under laminar and turbulent conditions, Atmos. Environ. 34, 2865-2871.
10. Grgić, I., Hudrik, V., Bizjak, M., and Levec, J., 1991: Aqueous S(IV) oxidation - I. Catalytic effects of some metal ions, Atmos. Environ. 25A (8), 1591-1597.
11. Hegg, D. A. and Hobbs, P. V., 1981: Cloud water chemistry and chemical production of sulfates in clouds, Atmos. Environ. 15, 1597-1604.
12. Hegg, D. A. and Hobbs, P. V., 1982: Measurements of sulfate production in natural clouds, Atmos. Environ. 16, 2663-2668.
13. Hegg, D. A., Hobbs, P. V., and Raschke, L. F., 1984: Measurements of the scavenging of sulfate and nitrate in clouds, Atmos. Environ. 18, 1939-1946.
14. Hoffmann, M. R. and Calvert, J. G., 1985: Chemical transformation modules for Eulerian acid deposition Models. II: The aqueous phase chemistry, NCAR, Boulder, Co.
15. Ibusuki, T. and Barnes, H. M., 1984: Manganese (II) catalysed sulfur dioxide oxidation in aqueous solution at environmental concentrations, Atmos. Environ. 18 (1), 145-151.
16. Kronig, R. and Brink, J. C., 1950: On the theory of extraction from falling droplets, J. Appl. Sci. Res. 2, 142-154.
17. 2 conversion in non-urban tropospheric clouds, J. Geophys. Res. 88 (C15), 10,721-10,732.
18. 4, in S. E. Schwartz and W. G. N. Slinn (eds), Precipitation Scavenging and Atmosphere - Surface Exchange, Hemisphere Publishing Corporation, Washington, 1, pp. 123-142.
19. Pruppacher, H. R., 1988: Auswaschen von atmosphärischen Spurenstoffen durch Wolken und Niederschlag mittels eines vertikalen Windkanals. BPT-Bericht 9/88, 62 pp. [available from G.S.F. Forschungszentrum Neuherberg, Ingoldstädter Landstr. 1, 85764 Oberschleissheim]
20. Pruppacher, H. R. and Klett, J. D., 1997: Microphysics of Clouds and Precipitation, 2nd edn., Kluwer Academic Publishers, Dordrecht, 954 pp.
21. Schmidkunz, H., 1969: Chemilumineszenz der Sulphitoxidation, PhD Thesis, Universität Frankfurt.
22. Seinfeld, J. H., 1986: Atmospheric Chemistry and Physics of Air Pollution, Wiley, New York, pp. 195-246.
23. Vohl, O., 1989: Die dynamischen Charakteristika des Mainzer vertikalen Windkanals, Thesis, Institut für Physik der Atmosphäre, Universität Mainz.
24. 2 absorption and desorption for water drops in air, J. Atmos. Chem. 1. 269-289.
25. 2 absorption and desorption for water drops in air, J. Atmos. Chem. 1, 291-306.
26. 2 in the ppb(v) range by water drops containing