Use of complexing agents for effective ion-exchange separation of Co(II)/Ni(II) from aqueous solutions

Water Research

Volumn 37, Issue 4, 2003, Pages 845-852

  Juang, Ruey Shin ^a   Wang, Yi Chieh ^a  

^a YUAN ZE UNIVERSITY   (Taiwan)

Author keywords

Cation exchange; Citrate; Co Ni separation; EDTA; IDA; NTA

Indexed keywords

ACETIC ACID; BINARY MIXTURES; PH; SOLUTIONS; WATER TREATMENT;

COMPLEXING AGENTS;

ION EXCHANGE;

CITRIC ACID; COBALT; DIGLYCINE; EDETIC ACID; METAL; NICKEL; NITRILOTRIACETIC ACID; WATER;

AQUEOUS SOLUTION; ION EXCHANGE; PH; SEPARATION;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL ANALYSIS; COMPLEX FORMATION; CONCENTRATION (PARAMETERS); ION EXCHANGE; PH; PRIORITY JOURNAL; SOLUBILITY;

EID: 0037296249     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0043-1354(02)00423-2     Document Type: Article

References (24)

1. Devi N.B., Nathsarma K.C., Chakravortty V. Separation and recovery of cobalt(II) and nickel(II) from sulfate solutions using sodium salts of D2EHPA, PC88A and Cyanex 272. Hydrometallurgy. 49:1998;47-61.
2. Sarangi K., Reddy B.R., Das R. Separation of Co(II)/Ni(II) by the sodium salts of D2EHPA, PC88A, and Cyanex 272 and their mixtures. Hydrometallurgy. 52:1999;253-265.
3. Zhang P.W., Yokoyama T., Itabashi O., Suzuki T.M., Inoue K. Hydrometallurgical process for recovery of metal values from spent lithium-ion secondary batteries. Hydrometallurgy. 47:1998;259-271.
4. Zhang P.W., Yokoyama T., Suzuki T.M., Inoue K. The synergistic extraction of nickel and cobalt with a mixture of di(2-ethylhexyl)phosphoric acid and 5-dodecylsalicyl-aldoxime. Hydrometallurgy. 61:2001;223-227.
5. Komasawa I., Otake T. Practical study of a solvent extraction process for separation of cobalt and nickel with 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester. J Chem Eng Jpn. 17:1984;417-423.
6. Danesi P.R., Reichley-Yinger L., Mason G., Kaplan L., Horwitz E.P., Diamond H. Selectivity-structure trends in the extraction of Co(II) and Ni(II) by dialkylphosphoric, alkyl alkylphosphonic, and dialkylphosphinic acids. Solvent Exch Ion Exch. 3:1985;435-452.
7. Ritcey GM, Ashbrook AW. In: Solvent extraction. principles and applications to process metallurgy, Vol. II. Amsterdam, The Netherlands: Elsevier, 1984. p. 279-361.
8. Bolto B.A., Pawlowski L. Wastewater treatment by ion exchange. 1987;E & FN Spon Ltd. New York.
9. 2+ ions by electrodialysis with a monovalent cation specific membrane and EDTA. J Membr Sci. 76:1993;39-49.
10. Huang T.C., Lin Y.K., Chen C.Y. Selective separation of nickel and copper from a complexing solution by a cation exchange membrane. J Membr Sci. 37:1987;131-144.
11. Huang T.C., Wang J.K. Selective transport of metals through cation exchange membrane in the presence of complexing agents. Ind Eng Chem Res. 32:1993;133-139.
12. Matsuyama H., Fujii K., Teramoto M. Selective separation of rare earth metals by Donnan dialysis in the presence of water-soluble complexing agent. J Chem Eng Jpn. 24:1991;253-255.
13. 2+ by electrodialysis by ion exchange membranes in the presence of EDTA. Sep Sci. 10:1975;307-322.
14. Kubal M., Machula T., Strnadova N. Separation of calcium and cadmium by electrodialysis in the presence of ethylenediaminetetraacetic acid. Sep Sci Technol. 33:1998;1969-1980.
15. Azis A., Matsuyama H., Teramoto M. Equilibrium and non-equilibrium extraction separation of rare earth metals in the presence of diethylenetriaminepentaacetic acid in aqueous phase. J Chem Eng Jpn. 28:1995;601-608.
16. Li L.Q., Wang C., Li Y.D. Separation of cobalt and nickel by emulsion liquid membranes using EDTA as masking reagent. J Membr Sci. 135:1997;173-177.
17. Matsuyama H., Komori K., Teramoto M. Selectivity enhancement in the permeation of rare earth metals through supported liquid membranes by the addition of diethylene-triaminepentaacetic acid to aqueous phase. J Membr Sci. 47:1989;217-228.
18. Conway M., Holoman S., Jones L., Leenhouts R., Williamson G. Selecting and using chelating agents. Chem Eng. 106(3):1999;86-90.
19. Morel FMM, Hering JG. In: Principles and Applications of Aquatic Chemistry. New York: Wiley, 1993. p. 332-43.
20. Korngold E., Belayev N., Aronov L., Titelman S. Influence of complexing agents on removal of metals from water by a cation exchanger. Desalination. 133:2001;83-88.
21. Juang R.S., Ju H.S. Effect of added complexing agents on extraction of Cu(II) from sulfate solutions by di(2-ethylhexyl)phosphoric acid. Sep Sci Technol. 36:2001;2499-2514.
22. Juang R.S., Huang I.P. Extraction of copper(II)-NTA chelated anions from water with Aliquat 336. Sep Sci Technol. 34:1999;2407-2420.
23. Allen H.E., Chen P.H. Remediation of metal contaminated soil by EDTA incorporating electrochemical recovery of metal and EDTA. Environ Prog. 12:1993;284-293.
24. Juang R.S., Wang S.W. Electrolytic recovery of binary metals and EDTA from strong complexed solutions. Water Res. 34:2000;3179-3185.