Electron spin resonance imaging of polymer degradation and stabilization

Progress in Polymer Science (Oxford)

Volumn 28, Issue 2, 2003, Pages 331-340

  Lucarini, Marco ^a   Pedulli, Gian Franco ^a   Motyakin, Mikhail V ^b   Schlick, Shulamith ^b  

^a UNIVERSITY OF BOLOGNA   (Italy)

^b University of Detroit Mercy   (United States)

Author keywords

Electron spin resonance; Electron spin resonance imaging; Hindered amine stabilizers; Poly(acrylonitrile butadiene styrene); Polymer degradation; Polypropylene

Indexed keywords

AMINES; FREE RADICALS; IMAGING TECHNIQUES; MORPHOLOGY; PARAMAGNETIC RESONANCE; PHOTODEGRADATION; PYROLYSIS; STABILIZERS (AGENTS);

HINDERED AMINE STABILIZERS;

ORGANIC POLYMERS;

EID: 0037290538     PISSN: 00796700     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0079-6700(02)00031-X     Document Type: Review

References (33)

1. O'Donnell J.H. Reichmanis E., O'Donnell J.H. The effects of radiation on high-technology polymers. 1989;1 American Chemical Society, Washington, DC. Chapter 1.
2. Hill D.J.T., Le T.T., O'Donnell J.H., Perera M.C.S., Pomery P.J. Reichmanis E., Frank C.W., O'Donnell J.H. Irradiation of polymeric materials: processes, mechanisms, and applications. 1993;American Chemical Society, Washington, DC.
3. Clough R.G., Billingham N.C., Gillen K.T. Advances in chemistry series 249. Advances in chemistry series 249. 1996;American Chemical Society, Washington, DC.
4. Hamid S.H. Handbook of polymer degradation. 2000;Marcel Dekker, New York.
5. Gillen K.T., Clough R.L. Polymer. 33:1992;4359.
6. Billingham N.C. Scott G. Atmospheric oxidation and antioxidants. vol. II:1993;219 Elsevier, Amsterdam. Chapter 4.
7. Eaton G.R., Eaton S.S., Ohno K. EPR imaging and in vivo EPR. 1991;CRC Press, Boca Raton, FL.
8. Schlick S., Eagle P., Kruczala K., Pilar J. Blümler P., Blümich B., Botto R., Fukushima E. Spatially resolved magnetic resonance: methods, materials, medicine, biology, rheology, ecology, hardware. 1998;221 Wiley, Weinheim. Chapter 17.
9. Lucarini M., Pedulli G.F., Borzatta V., Lelli N. X-band EPR imaging of polymers irradiated with UV light. Res Chem Intermed. 22:1996;581.
10. Lucarini M., Pedulli G.F. Use of EPR to image nitroxyl radicals in HALS stabilized polymers. Angew Makromol Chem. 252:1997;179.
11. Lucarini M., Pedulli G.F., Borzatta V., Lelli N. The determination of nitroxide radical distributions in polymers by EPR-imaging. Polym Degrad Stab. 53:1996;9.
12. Franchi P., Lucarini M., Pedulli G.F., Bonora M., Vitali M. Time evolution of the concentration profiles of HALS stabilizers and of the corresponding oxidation forms across polypropylene plaques irradiated with UV-visible light. Macromol Chem Phys. 202:2001;1246.
13. Motyakin M.V., Gerlock J.L., Schlick S. Electron spin resonance imaging (ESRI) of degradation and stabilization processes: behavior of a hindered amine stabilizer in UV-exposed poly(acrylonitrile-butadiene-styrene) (ABS) polymers. Macromolecules. 32:1999;5463.
14. Motyakin M.V., Gerlock J.L., Schlick S. Mallinson L.G. Ageing studies and lifetime extension of materials. 2001;353 Kluwer, New York.
15. Kruczala K., Motyakin M.V., Schlick S. 1D and 2D spatial-spectral electron spin resonance imaging (ESRI) of degradation and stabilization processes in poly(acrylonitrile-butadiene-styrene) (ABS). J Phys Chem B. 104:2000;3387.
16. Motyakin M.V., Schlick S. Spectral profiling by 1D and 2D electron spin resonance imaging: nitroxide radicals in UV and thermal degradation of poly(acrylonitrile-butadiene-styrene) containing a hindered amine stabilizer. Macromolecules. 34:2001;2854.
17. Motyakin M.V., Schlick S. Thermal degradation at 393K of poly(acrylonitrile-butadiene-styrene) containing a hindered amine stabilizer: A study by ATR-FTIR. Polym Degrad Stab. 76:2002;25.
18. Motyakin M.V., Schlick S. Electron spin resonance imaging (ESRI) and ATR-FTIR study of poly(acrylonitrile-butadiene-styrene) (ABS) containing a hindered amine stabilizer and thermally treated at 353 K. Macromolecules. 35:2002;3984.
19. Bokria J., Schlick S. Spatial effects in the photodegradation of poly(acrylonitrile-butadiene-styrene): a study by ATR-FTIR. Polymer. 43:2002;3239.
20. Gerlock J.L., Bauer D.R., Briggs L.M. Photo-stabilisation and photo-degradation in organic coating containing a hindered amine light stabiliser. Part I - ESR measurements of nitroxide concentration. Polym Degrad Stab. 14:1986;53.
21. Pospisil J. Aromatic and heterocyclic amines in polymer stabilization. Adv Polym Sci. 124:1995;87.
22. Degtyarev E.N., Schlick S. Diffusion coefficients of small molecules in various phases of pluronic L64 measured by one-dimensional electron spin resonance imaging (1D ESRI). Langmuir. 15:1999;5040.
23. Marek A. Unpublished work from this laboratory; 2000.
24. Maltempo M.M., Eaton S.S., Eaton G.R. Eaton G.R., Eaton S.S., Ohno K. EPR imaging and in vivo EPR. 1991;145 CRC Press, Boca Raton, FL. Chapter 14.
25. Malík J., Hrivík A., Tomová E. Diffusion of hindered amine light stabilizers in low density polyethylene and isotactic polypropylene. Polym Degrad Stab. 35:1992;61.
26. Rabek J.F. Photostabilisation of polymers, principles and applications. 1990;Elsevier, London.
27. Dudler V. Compatibility of HALS-nitroxides with polyolefines. Polym Degrad Stab. 42:1993;205.
28. Crank J. The mathematics of diffusion. 2nd ed: 1975;Clarendon Press, Oxford.
29. Kulich D.M., Pace J.E., Fritch L.W. Jr., Brisimitzakis A. Kroschkowitz J. 4th ed Kirk-Othmer encyclopedia of chemical technology. vol. 1:1991;391 Wiley, New York.
30. Aoki Y., Hatano A., Tanaka T., Watanabe H. Nonlinear stress relaxation of ABS polymers in the molten state. Macromolecules. 34:2001;3100.
31. Steeman P.A.M., Meier R.J., Simon A., Gast J. The structure of a styrene-acrylonitrile/butadiene polymer studied by 2D-IR spectroscopy. Polymer. 38:1997;5455.
32. Kulich D.M., Gaggar S.K. Clough R.G., Billingham N.C., Gillen K.T. Advances in chemistry series 249. Advances in chemistry series 249. 1996;483 American Chemical Society, Washington, DC. Chapter 31.
33. Jouan X., Gardette J.L. Photo-oxidation of ABS at long wavelengths. J Polym Sci A, Polym Chem. 29:1991;685.