Gas chromatographic-mass spectrometric method for the determination of bisphenol A and its chlorinated derivatives in urban wastewater

Water Research

Volumn 37, Issue 4, 2003, Pages 735-742

  Zafra, Alberto ^a   Del Olmo, Monsalud ^a   Suárez, Beatriz ^a   Hontoria, Ernesto ^a   Navalón, Alberto ^a   Vílchez, José Luís ^a,b  

^a UNIVERSITY OF GRANADA   (Spain)

^b UNIVERSITY OF GRANADA   (Spain)

Author keywords

Bisphenol A; Bisphenol A chlorinated derivatives; Gas chromatography mass spectrometry; Liquid liquid extraction; Silylation; Wastewater analysis

Indexed keywords

CHLORINE; EXTRACTION; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; SILANES;

ENDOCRINE DISRUPTERS;

WASTEWATER;

4,4' ISOPROPYLIDENEDIPHENOL; ANTHRACENE; CARBON TETRACHLORIDE; DICHLOROMETHANE; N,O BIS(TRIMETHYLSILYL)TRIFLUOROACETAMIDE; SOLVENT; TRIFLUOROACETAMIDE DERIVATIVE; UNCLASSIFIED DRUG;

CHLORINATION; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; WASTEWATER;

ANALYTIC METHOD; AQUEOUS SOLUTION; ARTICLE; ASSAY; CHLORINATION; CONCENTRATION RESPONSE; GAS CHROMATOGRAPHY; LIQUID LIQUID EXTRACTION; MASS SPECTROMETRY; METHODOLOGY; PRIORITY JOURNAL; SAMPLING; SILYLATION; STANDARD; VALIDATION PROCESS; WASTE WATER;

EID: 0037289658     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0043-1354(02)00413-X     Document Type: Article

References (18)

1. Helaleh M.I.H., Takabayashi Y., Fujii S., Korenaga T. Gas chromatographic-mass spectrometric method for separation and detection of endocrine disruptors from environmental water samples. Anal Chim Acta. 428:2001;227-234.
2. Steinmetz R., Mitchner N.A., Grant A., Allen D.L., Bigsby R.M., Ben-Jonathan N. The xenoestrogen bisphenol A induces growth, differentiation, and c-fos gene expression in the female reproductive tract. Endocrinology. 136:1998;2741-2747.
3. Mol H.G.J., Sunarto S., Steijger O.M. Determination of endocrine disruptors in water after derivatization with N-methyl-N-(tert-butyldimethiltrifluoroacetamide) using gas chromatography with mass spectrometric detection. J Chromtogr A. 879:2000;97-112.
4. Fürhacker M., Scharf S., Weber H. Bisphenol A. emissions from point sources Chemosphere. 41:2000;751-756.
5. Pulgar R., Olea-Serrano M.F., Novillo-Fertrell A., Rivas A., Pazos P., Pedraza V., Navajas J.M., Olea N. Determination of bisphenol A and related aromatic compounds released from bis-GMA-based composites and sealants by high performance liquid chromatography. Environ Health Perspect. 108:2000;195-202.
6. Olea N., Olea-Serrano M.F. Oestrogen and the environment. Eur J. Cancer Prevent. 5:1996;491-496.
7. Richardson S.D., Thruston A.D., Caughran T.V., Chen P.H., Collette T.W., Floyd T.L., Schenck K.M., Lykins B.W., Sun G.R., Majetich G. Identification of new drinking water disinfection byproducts formed in the presence of bromide. Environ Sci Technol. 33:1999;3378-3383.
8. Zafra A, González-Casado A, del Olmo M, Fernández J, Fernández M, Olea N, Vílchez JL. Identification of bisphenol-A chloroderivatives in chlorinated drinking water. Estrogenic properties. J Chromatogr A 2002, in press.
9. González-Casado A., Navas N., del Olmo M., Vílchez J.L. Determination of bisphenol A in water by microliquid-liquid extraction followed by silylation and GC-MS. J Chromatogr Sci. 36:1998;565-569.
10. Statgraphics Plus for Windows. Version 4.1. Manugistics Inc. and Statistical Graphics Corporation, Rockville, MD, USA, 1999.
11. Cela R (coord.). Avances en Quimiometría Práctica. Universidad de Santiago de Compostela, Servicio de Publicaciones e Intercambio Científico Santiago de Compostela, 1994.
12. Garcia Campaña A.M., Cuadros-Rodríguez L., Alés Barrero F., Román Ceba M., Sierra Fernández J.L. A chemometric program to check analytical method performance and to assess the trueness by standard addition methodology. Trends Anal Chem. 16:1997;381-385.
13. Knapp D.R. Handbook of analytical derivatization reactions. 1979;Wiley, New York.
14. Box G.E.P., Hunter W.G., Hunter J.S. Statistics for experimenters. an introduction to desing, data analysis and model building:1978;Wiley, New York.
15. Analytical Methods Committee. Is my calibration linear? The Analyst 1994;119:2363-6.
16. González-Casado A., Cuadros-Rodríguez L., Hernández E.A., Vílchez J.L. Estimate of gas chromatographic blanks. Application to detection limits evaluation as recommended by IUPAC. J Chromatogr A. 726:1996;133-139.
17. Cuadros-Rodríguez L., García Campaña A.M., Alés F., Jiménez C., Román M. Validation of an analytical instrumental method by standard addition methodology. J Assoc Off Anal Chem. 78:1995;471-476.
18. Cardone M.J. New technique in chemical assay calculations. 2. Correct solutions of the model problem and related concepts. Anal Chem. 58:1986;438-445.