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Volumn 236, Issue 1-2, 2003, Pages 15-33

The organometallic chemistry of Ph3P=C=C=O. A route to metal-substituted ketenes

Author keywords

1 Ketenyl complexes; Ketenes; Ketenylidenetriphenylphosphorane; Metal substituted ketenes; Ph3PCCO; Ylides

Indexed keywords

COORDINATION COMPOUND; DIMER; KETENE DERIVATIVE; KETENYLIDENETRIPHENYLPHOSPHORANE; METAL COMPLEX; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

EID: 0037269863     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0010-8545(02)00158-3     Document Type: Review
Times cited : (28)

References (120)
  • 5
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    • G.M. Kosolapoff, L. Maier (Eds.), Wiley-Interscience, New York
    • see for example: (a) H.J. Bestmann, R. Zimmermann, in: G.M. Kosolapoff, L. Maier (Eds.), Organic Phosphorus Compounds, Wiley-Interscience, New York, 1972, pp. 1-184;
    • (1972) Organic Phosphorus Compounds , pp. 1-184
    • Bestmann, H.J.1    Zimmermann, R.2
  • 13
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    • note
    • Rather strangely, the paper reporting X-ray structure determination of 1 (Ref. [9]) was received by the Editors in June 21, 1966 and it reports, for the synthesis of this compound, a contribution of Birum and Mattew appeared in the Abstracts of 152nd National Meeting of the A.C.S. held in New York in September 1966! The paper reporting the complete synthesis and characterization of 1 (Ref. [8]) was received by the Editors in August 27, 1966 and indicates Ref. [9] as in press.
  • 20
    • 0013101566 scopus 로고    scopus 로고
    • note
    • -1, with little differences between spectra measured in solid or in solution.
  • 21
    • 0013056376 scopus 로고    scopus 로고
    • unpublished results
    • L. Pandolfo, unpublished results.
    • Pandolfo, L.1
  • 31
    • 0001768316 scopus 로고
    • βremarkably stable and do not dimerize. The interested reader may refer to the following references: (a) D.-c. Zhao, A.D. Allen, T.T. Tidwell, J. Am. Chem. Soc. 115 (1993) 10097;
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 10097
    • Zhao, D.-C.1    Allen, A.D.2    Tidwell, T.T.3
  • 76
  • 101
    • 0013112484 scopus 로고    scopus 로고
    • note
    • These coordinatively unsaturated species resulted from the breaking of halogen bridged dimeric compounds, or from displacement of coordinated solvent or other easily removable ligands by 1.
  • 103
    • 0013150659 scopus 로고
    • Dissertation Thesis, University of Padova, Italy, A.A.
    • K.L. Dragani, Dissertation Thesis, University of Padova, Italy, A.A., 1994-1995.
    • (1994)
    • Dragani, K.L.1
  • 105
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    • John Wiley & Sons, Inc, New York
    • T.T. Tidwell, Ketenes, John Wiley & Sons, Inc, New York, 1995.
    • (1995)
    • Tidwell, T.T.1    Ketenes2
  • 118
    • 0013057627 scopus 로고    scopus 로고
    • note
    • 2O.
  • 120
    • 0013055877 scopus 로고    scopus 로고
    • note
    • 3P=C=C=O π orbitals are mainly localized on the carbonyl C atom (Ref. [25]), i.e. quite far from the metal.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.