Synthesis, structure, and reactivity of a new mononuclear molybdenum(VI) complex resembling the active center of molybdenum oxotransferases

European Journal of Inorganic Chemistry

Volumn , Issue 2, 2003, Pages 363-369

  Dinda, Rupam ^a   Sengupta, Parbati ^a   Ghosh, Saktiprosad ^a   Sheldrick, William S ^b  

^a DEPARTMENT OF MATERIALS SCIENCE   (India)

^b RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

Bioinorganic chemistry; Enzyme models; Molybdenum; Substrate binding

Indexed keywords

BIOCHEMISTRY; CHELATION; GAMMA RAYS; X RAY CRYSTALLOGRAPHY;

ACTIVE CENTER; BINDING CAPACITIES; BIOINORGANIC CHEMISTRY; DESIGN STRUCTURE; DESIGN SYNTHESIS; DONOR LIGANDS; ENZYME MODELS; OCTAHEDRAL COMPLEX; STRUCTURE DETERMINATION; SUBSTRATE-BINDING;

MOLYBDENUM COMPOUNDS;

MOLYBDENUM COMPLEX;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; DRUG ISOLATION; ENZYME ACTIVE SITE; ORGANIC CHEMISTRY; OXYGEN TRANSPORT; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY ANALYSIS;

EID: 0037266454     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200390049     Document Type: Article

References (33)

1. R. H. Holm, Coord. Chem. Rev. 1990, 100, 183-221.
2. R. H. Holm, J. M. Berg, Acc. Chem. Res. 1986, 19, 363-370.
3. J. M. Berg, R. H. Holm, J. Am. Chem. Soc. 1985, 107, 917-925.
4. B. E. Schultz, S. F. Gheller, M. C. Muetterties, M. J. Scott, R. H. Holm, J. Am. Chem. Soc. 1993, 115, 2714-2722.
5. S. Purohit, A. P. Koley, L. S. Prasad, P. T. Manoharan, S. Ghosh, Inorg. Chem. 1989, 28, 3735-3742.
6. H. Oku, N. Ueyama, A. Nakamura, Bull. Chem. Soc. Jpn. 1999, 72, 2261-2270.
7. J. M. Berg, R. H. Holm, J. Am. Chem. Soc. 1985, 107, 925-932.
8. R. Dinda, P. Sengupta, T C. W. Mak, S. Ghosh, Inorg. Chem. 2002, 41, 1684-1688.
9. [9a] W. Kemp, Organic Spectroscopy, Macmillan, Hampshire, 1987, p. 62.
10. [9b] K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1986, p. 241.
11. S. Ghosh, T. K. Bandyopadhyay, P. K. Ray, M. S. Mitra, J. Inorg. Biochem. 1984, 20, 79-86.
12. N. S Biradar, B. R. Havinale, Inorg. Chim. Acta 1976, 17, 157-160.
13. J. Liimatainen, A. Lehtonen, R. Sillanpaa, Polyhedron 2000, 19, 1133-1138.
14. F. J. Arnaiz, R. Aguado, M. R. Podrosa, A. D. Cian, J. Fischer, Polyheron. 2000, 19, 2141-2147.
15. A. Rana, R. Dinda, P. Sengupta, L. R. Falvello, S. Ghosh, Polyhedron 2002, 21, 1023-1030.
16. [15a] S. Purohit, A. P. Koley, S. Ghosh, Polyhedron. 1990, 9, 881-890.
17. [15b] S. Purohit, S. Ghosh, J. Chem. Res. 1988, 158-159.
18. C. Bustos, O. Burckhardt, R. Schrebler, D. Carrillo, A. M. Arif, A. H. Cowley, C. M. Nunn, Inorg. Chem. 1990, 29, 3996-4001.
19. J. Topich, Inorg. Chem. 1981, 20, 3704-3707.
20. N. S. Rao, D. D. Mishra, R. C. Maurya, N. N. Rao, Bull. Chem. Soc. Jpn. 1995, 68, 1589-1592.
21. M. Chaudhury, J. Chem. Soc., Dalton Trans. 1984, 115-120.
22. J. M. Berg, R. H. Holm, J. Am. Chem. Soc. 1984, 106, 3035-3036.
23. S. K. Dutta, D. B. McConville, W. J. Youngs, M. Chaudhury, Inorg. Chem. 1997, 36, 2517-2522.
24. R. Hille, Chem. Rev. 1996, 96, 2757-2816.
25. M. J. Romao, M. Archer, J. Moura, J. J. G. Moura, J. Legall, R. Engh, M. Scheneidar, M. Hof, P. Hof, R. Huber, Science 1995, 270, 1170-1176.
26. J. Topich, J. T. Lyon, Inorg. Chem. 1984, 23, 3202-3206.
27. E. I. Stiefel, Prog. Inorg. Chem. 1977, 22, 102.
28. R. N. Jowitt, P. C. H. Mitchell, J. Chem. Soc. A 1969, 2632-2636.
29. I. W. Boyd, J. T. Spence, Inorg. Chem. 1982, 21, 1602-1606.
30. B. B. Kaul, J. H. Enemark, S. L. Merbs, J. T. Spence, J. Am. Chem. Soc. 1985, 107, 2885-289.
31. G. J. J. Chen, J. W. McDonald, W. E. Newton, Inorg. Chem. 1976, 15, 2612-2615.
32. D. T. Sawyer, J. L. Roberts, Experimental Electrochemistry for Chemists, John Wiley & Sons, New York, 1974, p. 212.
33. G. M. Sheldrick, SHELX-97, Programs for structure solution and refinement, Göttingen, Germany, 1997.