Identification of radiolytic degradation products of γ-irradiated 30% trialkylphosphine oxide-kerosene solution

Solvent Extraction and Ion Exchange

Volumn 21, Issue 1, 2003, Pages 91-108

  Zhang, Ping ^a   Song, C L ^a   Liang, J F ^a   Xin, R X ^a  

^a TSINGHUA UNIVERSITY   (China)

Author keywords

ESI MS; Radiolysis; TRPO

Indexed keywords

EXTRACTION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GAMMA RAYS; MASS SPECTROMETRY; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; RADIOLYSIS;

RADIOLYTIC DEGRADATION;

OXIDES;

KEROSENE; MASS SPECTROMETRY; RADIOACTIVE WASTE; SOLVENT EXTRACTION;

EID: 0037260337     PISSN: 07366299     EISSN: None     Source Type: Journal    
DOI: 10.1081/SEI-120017549     Document Type: Article

References (16)

1. Van Tuyle, G.J.; Todosow, M.; Geiger, M.J. Accelerator-driven subcritical target concept for transmutation of nuclear waste. Nucl. Technol. 1993, 101 (1), 1-17.
2. Schulz, W.W.; Horwitz, E.P. The extraction and recovery of plutonium and americium from nitric acid waste solutions by the TRUEX process: continuing development studies. ANL 85-43 Argonne National Laboratory, Sep. 1985.
3. Cuillerdier, C.; Musikas, C.; Hoel, P. Malonamide as new extractants for nuclear waste solution. Sep. Sci. Technol. 1991, 26, 1229-1244.
4. Morita, Y.; Fujiwara, T.; Shirahashi, K. Diisodecylphosphoric acid, DIDPA, as an extractant for transuranium elements. In Global'95, International Conference on Evaluation of Emerging Nuclear Fuel Cycle Systems; The French Section of ANS and the Fuel Cycle and Waste Management Division: Versailles, France, 1995; Vol. 1, 1163-1171.
5. Kubota, M.; Yanayucki, I.K.; Shirahashi, K. Development of a partitioning process for the management of high level waste. In Global'93, Future Nuclear Systems: Emerging Fuel Cycles & Waste Disposal Options; American Nuclear Society: Seattle, USA, 1993; Vol. 1, 588-594.
6. Liljenzin, J.O.; Persson, G.; Svantesson, I. The CTH process for HLLW treatment part I: General description and process design. Radiochim. Acta 1984, 35, 155-162.
7. Zhu, Y.J. Extraction by trialkyphosphine oxide-an effective method of recovering actinides from HLLW (in Chinese). J. Tsinghua University 1992, 32 (6), 1-12.
8. Bush, R.P.; Mills, A.L.; Stearn, M.L. Comparison of the plant requirements, process performance and waste arising for potential processes for the partitioning of high level waste. In Global'95, International Conference on Evaluation of Emerging Nuclear Fuel Cycle Systems; The French Section of ANS and the Fuel Cycle and Waste Management Division: Versailles, France, 1995; Vol. 1, 232-239.
9. Zhang, P.; Song, C.L.; Liang, C.F.; Xin, R.X. Extraction and retention of plutonium with γ-irradiated 30% trialkylphosphine oxide-kerosene solution. Solvent Extr. Ion Exch. 2001, 19 (1), 79-89.
10. Zhang, P.; Liang, J.F.; Song, C.L.; Xin, R.X. Extraction and retention of technetium with γ-irradiated 30% trialkylphosphine oxide-kerosene solution. Atomic Energy Science and Technology (in Chinese) 2001, 35 (4), 337-343.
11. Xin, R.X.; Song, C.L.; Jiao, J.X.; Liang, J.F. Gas chromatographic study of the radiolytic products of trialkylphosphine oxide. Chinese Journal of Spectroscopy Laboratory 1999, 16 (5), 498.
12. Nissen, W.M. Liquid Chromatography-Mass Spectrometry; Marcel Dekker Inc.: New York, 1999.
13. Lamouroux, C.; Virelizier, H.; Moulin, C.; et al. Direct determination of dibutyl and monobutyl phosphate in a tributyl phosphate/nitric aqueousphase system by electrospray mass spectrometry. Anal. Chem. 2000, 72, 1186-1191.
14. Berthon, L.; Piveteau, B. Contribution of electrospray mass spectrometry to the study of the organic species and metal-ligand complexes in solution. In Atalante 2000, Scientific Research on the Back-end of the Fuel Cycle for the 21st Century; Oct 24-26, 2000; Paris, France.
15. Wu, J.L.; Qi, S.C. Radiation Chemistry (in Chinese); Atomic Energy Press: Beijing, 1993.
16. Tahraoui, A.; Morris, J.H. Decomposition of solvent extraction media during nuclear reprocessing: Literature review. Sep. Sci. Technol. 1995, 30 (13), 2603-2630.