Sterically encumbered porphyrins by Suzuki reactions of a 5,15-bis(4,6-dichloropyrimidin-5-yl) derivative

Synlett

Volumn , Issue 1, 2003, Pages 79-82

  Maes, W ^a   Dehaen, W ^a  

^a UNIVERSITY OF LEUVEN   (Belgium)

Author keywords

Arylations; Palladium; Porphyrins; Steric hindrance; Suzuki cross coupling

Indexed keywords

1 NAPHTHYLBORONIC ACID; 2 NAPHTHYLBORONIC ACID; 4 PHENOXYPHENYLBORONIC ACID; 5,15 BIS(4,6 DICHLOROPYRIMIDIN 5 YL) DERIVATIVE; 5,15 BIS(PYRIMIDINYL)PORPHYRIN; BENZENEBORONIC ACID; BORONIC ACID DERIVATIVE; PALLADIUM; PORPHYRIN DERIVATIVE; PYRIMIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ARYLATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; STEREOSPECIFICITY; SUZUKI REACTION; SYNTHESIS;

EID: 0037238617     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

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39. max = 432.6 (log ε = 5.586), 528.2 (log ε = 4.271), 564.3 (log ε = 4.025), 603.0 (log ε = 3.829), 662.2 (log ε = 3.673). The optical spectra are extremely similar to the one of the starting porphyrin 1 but are red-shifted for about 12-16 nm. Suslick et al. reported the same red-shift (ca. around 30 nm) for their porphyrin compared to the tetraphenylporphyrin.
40. All arylboronic acids were purchased from Acros.