Rate-determining steps, rate-determining parameters, and apparent activation energy of stepwise reactions. 1. Stepwise non-catalytic reactions linear in respect to intermediates

Reaction Kinetics and Catalysis Letters

Volumn 78, Issue 1, 2003, Pages 139-150

  Parmon, V N ^a,b  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

^b NOVOSIBIRSK STATE UNIVERSITY   (Russian Federation)

Author keywords

Apparent activation energy; Rate determining; Steady occurrence; Stepwise reactions

Indexed keywords

ACTIVATION ENERGY; CATALYSIS; MATHEMATICAL MODELS; NUMERICAL ANALYSIS; PROCESS CONTROL;

NON-CATALYTIC REACTIONS; RATE DETERMINING PARAMETERS; STEPWISE REACTIONS;

RATE CONSTANTS;

EID: 0037218564     PISSN: 01331736     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1022578303294     Document Type: Article

References (6)

1. K.A. Connors: Chemical Kinetics, VCH Publishers, New York 1990.
2. A.D. McNaught, A. Wilkinson: Compendium of Chemical Terminology, IUPAC Recommendations, p. 339 Blackwell, Oxford 1997.
3. V.N. Parmon: Catalysis Today, 51, 435 (1999).
4. N.M. Bazhin, V.A. Ivanchenko, V.N. Parmon: Thermodynamics for Chemists (A Textbook). Khimiya, Moscow 2000.
5. I. Prigogine, P. Defey: Chemical Thermodynamics, Oxford 1961.
6. S.R. DeGroot, P. Mazur: Non-Equilibrium Thermodynamics, North-Holland Publishing Company, Amsterdam 1962.