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Volumn 106, Issue 43, 2002, Pages 10162-10173

High-temperature Raman investigation of concentrated sulfuric acid mixtures: Measurement of H-bond ΔH values between H3O+ or H5O2+ and HSO4-

Author keywords

[No Author keywords available]

Indexed keywords

ISOTHERMAL PRESSURES;

EID: 0037206720     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp021436z     Document Type: Article
Times cited : (17)

References (28)
  • 3
    • 0003807875 scopus 로고
    • McGraw-Hill: New York
    • The data of reference 1 as treated in Lewis, G.N.; Randall, M. Thermodynamics and the Free Energy of Chemical Substances; McGraw-Hill: New York, 1923; p 95, Table 7, were subjected to least-squares analysis using a seventh-degree polynomial. Data of reference 2 were subjected to least-squares analysis using a fifth-degree polynomial.
    • (1923) Thermodynamics and the Free Energy of Chemical Substances , pp. 95
    • Lewis, G.N.1    Randall, M.2
  • 9
    • 0011311631 scopus 로고
    • Klotz, I.M.; Eckert, C.F. J. Am. Chem. Soc. 1942, 64, 1878. Young, T.F.; Singleterry, C.R.; Klotz, I.M. J. Phys. Chem. 1978, 82, 671.
    • (1942) J. Am. Chem. Soc. , vol.64 , pp. 1878
    • Klotz, I.M.1    Eckert, C.F.2
  • 12
    • 0004165770 scopus 로고
    • Dore, J.C., Teixeira, J., Eds.; Kluwer Academic: Dordrecht, The Netherlands
    • Walrafen, G.E. Hydrogen-Bonded Liquids; Dore, J.C., Teixeira, J., Eds.; Kluwer Academic: Dordrecht, The Netherlands, 1990.
    • (1990) Hydrogen-Bonded Liquids
    • Walrafen, G.E.1
  • 18
    • 0011350436 scopus 로고    scopus 로고
    • note
    • Considerable effort has been expended (Walrafen) in an attempt to find Raman evidence for charged species in, and above, various acid solutions at very high temperatures, but with negative results. This failure may be related to the fact that the attractive forces between oppositely charged ions are strong when the dielectric constant is low.
  • 23
    • 0011311632 scopus 로고
    • Franks, F., Ed.; Cambridge University Press: Cambridge, U.K.
    • Ratcliff, C.I.; Irish, D.E. In Water Science Reviews; Franks, F., Ed.; Cambridge University Press: Cambridge, U.K., 1961; p 161.
    • (1961) Water Science Reviews , pp. 161
    • Ratcliff, C.I.1    Irish, D.E.2
  • 27
    • 0004047252 scopus 로고
    • Water: A comprehensive treatise; Franks, F., Ed.; Plenum Press: New York
    • Tödheide, K. In The Physics and Physical Chemistry of Water; Water: A Comprehensive Treatise; Franks, F., Ed.; Plenum Press: New York, 1972; Vol. 1.
    • (1972) The Physics and Physical Chemistry of Water , vol.1
    • Tödheide, K.1


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