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Volumn 124, Issue 43, 2002, Pages 12889-12897

Hydrogen-bonded macrocluster formation of ethanol on silica surfaces in cyclohexane

Author keywords

[No Author keywords available]

Indexed keywords

SURFACE CLUSTERS;

EID: 0037202219     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027141g     Document Type: Article
Times cited : (84)

References (36)
  • 1
    • 0033235115 scopus 로고    scopus 로고
    • Hydrogen-Bonded Macroclusters at the Solid-Liquid Interfaces I. Preliminary accounts of this work: Mizukami, M.; Kurihara, K. Chem. Lett. 1999, 1005-1006.
    • (1999) Chem. Lett. , pp. 1005-1006
    • Mizukami, M.1    Kurihara, K.2
  • 5
    • 0030848621 scopus 로고    scopus 로고
    • Decher, G. Science 1997, 277, 1232-1237.
    • (1997) Science , vol.277 , pp. 1232-1237
    • Decher, G.1
  • 29
    • 2142685700 scopus 로고    scopus 로고
    • note
    • Here, we used the term "similar to the capillary force" to describe the mechanism of the long-range attraction, i.e., the interfacial energy between the ethanol adsorption layer and the bulk solution caused the long-range attraction similarly to the capillary force. The capillary force is the attraction caused by the bridging of condensed liquid in a capillary between the surfaces close to contact. The condensation of ethanol in our study was caused by hydrogen-bonding interactions between surface silanol groups and ethanol hydroxyl groups as well as between ethanol molecules, which is different from the ordinary mechanism of the capillary condensation.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.