Enhanced enantio- and diastereoselectivity via confinement and cation binding: Yang photocyclization of 2-benzoyladamantane derivatives within zeolites

Journal of Organic Chemistry

Volumn 67, Issue 24, 2002, Pages 8339-8350

  Natarajan, Arunkumar ^a   Joy, Abraham ^a   Kaanumalle, Lakshmi S ^a   Scheffer, John R ^b   Ramamurthy, V ^a  

^a Tulane University   (United States)

^b UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALINITY; CARBOXYLIC ACIDS; PHOTOCHEMICAL REACTIONS;

ENANTIOSELECTIVITY;

ZEOLITES;

2 BENZOYLADAMANTANE DERIVATIVE; ADAMANTANE DERIVATIVE; ALKALI METAL; BUTANOL; CARBOXYLIC ACID DERIVATIVE; CYCLOBUTANOL; PSEUDOEPHEDRINE; UNCLASSIFIED DRUG; ZEOLITE;

AB INITIO CALCULATION; ARTICLE; CATION TRANSPORT; CHEMICAL BINDING; CYCLIZATION; DIASTEREOISOMER; ENANTIOSELECTIVITY; HYDROGEN BOND; MATHEMATICAL COMPUTING; MOLECULAR INTERACTION; PHOTOCHEMICAL EFFICIENCY; REACTION ANALYSIS; STEREOISOMERISM; THERMAL ANALYSIS;

EID: 0037195714     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0260793     Document Type: Article

References (62)

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20. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
21. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
22. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
23. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
24. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
25. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
26. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
27. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
28. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
29. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
30. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
31. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
32. The use of zeolites to enhance chiral induction in thermal reactions is also being explored by several groups: (a) Thomas, J. M.; Maschmeyer, T.; Johnson, B. F. G.; Shephard, D. S. J. Mol. Catal. A. Chem. 1999, 141, 139. (b) Thomas, J. M.; Raja, R. J. Chem. Soc., Chem. Commun. 2001, 675. (c) Hutchings, G. J. J. Chem. Soc., Chem. Commun. 1999, 301. (d) Clark, J. H.; Macquarrie, D. J. J. Chem. Soc., Chem. Commun. 1998, 853. (e) Johnson, B. F. G.; Raynor, S. A.; Shephard, D. S.; Mashmeyer, T.; Thomas, J. M.; Sankar, G.; Bromley, S.; Oldroyd, R.; Gladden, L.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 1999, 1167. (f) Raynor, S. A.; Thomas, J. M.; Raja, R.; Johnson, B. F. G.; Bell, R. G.; Mantle, M. D. J. Chem. Soc., Chem. Commun. 2000, 1925. (g) De Vos, D. E.; Meinershagen, J. L.; Bein, T. Angew. Chem., Int. Ed. Engl. 1996, 35, 2211. (h) Ogunwumi, S. B.; Bein, T. J. Chem. Soc., Chem. Commun. 1997, 901. (i) Corma, A.; Iglesias, M.; del Pino, C.; Sanchez, F. J. Chem. Soc., Chem. Commun. 1991, 1253. (j) Zhou, X. E.; Yu, X. Q.; Huang, J. S.; Che, C. M.; Li, S. G.; Li, L. S. J. Chem. Soc., Chem. Commun. 1999, 1789. (k) Paola, P.; Langham, C.; McMorn, P.; Bethell, D.; Bulman-Page, P. C.; Hancock, F. E.; Sly, C.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 143. (l) Paola, P.; McMorn, P.; Murphy, D.; Bethell, D.; Page, P. C. B.; Hancock, F. E.; Sly, C.; Kerton, O. J.; Hutchings, G. J. J. Chem. Soc., Perkin Trans. 2 2000, 2008. (m) Kim, G. J.; Park, D. W. Catal. Today 2000, 63, 537.
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