Adsorption of a benzylic amide macrocycle on a solid substrate: XPS and HREELS characterization of thin films grown on Au(111)

Journal of Physical Chemistry B

Volumn 106, Issue 34, 2002, Pages 8739-8746

  Whelan, Caroline M ^a,b   Cecchet, Francesca ^a   Baxter, Richard ^c,d   Zerbetto, Francesco ^b   Clarkson, Guy J ^e   Leigh, David A ^e   Rudolf, Petra ^a  

^a UNIVERSITY OF NAMUR   (Belgium)

^b IMEC   (Belgium)

^c UNIVERSITY OF BOLOGNA   (Italy)

^d UNIVERSITY OF OXFORD   (United Kingdom)

^e UNIVERSITY OF WARWICK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; BENZENE; BINDING ENERGY; CHEMICAL BONDS; CHEMISORPTION; ELECTRON ENERGY LOSS SPECTROSCOPY; FILM GROWTH; GOLD; MOLECULAR ORIENTATION; MOLECULAR VIBRATIONS; VAPOR DEPOSITION; X RAY PHOTOELECTRON SPECTROSCOPY;

MACROCYCLES;

THIN FILMS;

EID: 0037194945     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp020338a     Document Type: Article

References (54)

1. Anelli, P.-L.; Spencer, N.; Stoddart, J.F. J. Am. Chem. Soc. 1991, 113, 5131.
2. Bissell, R.A.; Córdova, E.; Kaifer, A.E.; Stoddart, J.F. Nature 1994, 369, 133.
3. Collin, J.-P.; Gavinã, P.; Sauvage, J.-P. New J. Chem. 1996, 21, 525.
4. Lane, A.S.; Leigh, D.A.; Murphy, A. J. Am. Chem. Soc. 1997, 119, 11092.
5. Murakami, H.; Kawabuchi, A.; Kotoo, K.; Kunitake, M.; Nakashima, N. J. Am. Chem. Soc., 1997, 119, 7605.
6. Kelly, T.R.; Bowyer, M.C.; Vijaya Bhaskar, K.; Bebbington, D.; Garcia, A.; Lang, F.; Kim, M.H.; Jette, M.P. J. Am. Chem. Soc. 1994, 116, 3657.
7. Kelly, T.R.; Tellitu, I.; Sestelo, J.P. Angew. Chem., Int. Ed. Engl. 1997, 36, 1866.
8. Davis, A.P. Angew. Chem., Int. Ed. Engl. 1998, 37, 909.
9. Bedard, T.C.; Moore, J.S. J. Am. Chem. Soc. 1995, 117, 10662.
10. Kelly, T.R.; De Silva, H.; Silva, R.A. Nature 1999, 401, 150.
11. Koumura, N.; R.W. Zijlstra, J.; van Delden, R.A.; Harada, N.; Feringa, B.L. Nature 1999, 401, 152.
12. Feynman, R.P. In Miniaturization; Gilbert, H.D., Ed.; Reinhold: New York, 1961.
13. Mislow, K. Chemtracts: Org. Chem. 1989, 2, 151.
14. Balzani, V.; Gómez-López, M.; Stoddart, J.F. Acc. Chem. Res. 1998, 31, 405.
15. Sauvage, J.-P. Acc. Chem. Res. 1998, 31, 611.
16. Gimzewski, J. Phys. World 1998, 11, 29.
17. Sauvage, J.-P., Dietrich-Buchecker, C.O. Eds. Molecular Catenanes, Rotaxanes and Knots; Wiley-VCH: Weiheim, 1999.
18. Clarkson, G.J.; Lacy, S.; Leigh, D.A.; Nepogodiev, S.; Slawin, A.M.Z.; Wong, J.Y.K. In preparation.
19. Johnston, A.G.; Leigh, D.A.; Murphy, A.; Smart, J.P.; Deegan, M.D. J. Am. Chem. Soc. 1996, 118, 10662.
20. Whelan, C.M.; Barnes, C.J.; Pireaux, J.-J. In preparation.
21. Thiry, P.A.; Pireaux, J.-J.; Caudano, R. Phys. Mag. 1981, 4, 35.
22. Moulder, J.F.; Stickle, W.F.; Sobol, P.E.; Bomben, K.D. Handbook of Photoelectron Spectroscopy; Perkin-Elmer Corporation, Physical Electronics Division: Eden Prairie, MN 55344, 1992.
23. Bermudez, V.; Capron, N.; Gase, T.; Gatti, F.G.; Kajzar, F.; Leigh, D.A.; Zerbetto, F.; Zhang, S. Nature 2000, 406, 608.
24. Fustin, C.-A.; Leigh, D.A.; Rudolf, P.; Timpel, D.; Zerbetto, F. Chem. Phys. Chem. 2000, 1, 97.
25. Leigh, D.A.; Parker, S.F.; Timpel, D.; Zerbetto, F. J. Chem. Phys. 2001, 114, 5006.
26. Allinger, N.L.; Yuh, Y.H.; Lii, J.-H. J. Am. Chem. Soc. 1989, 111, 8551.
27. Lii, J.-H.; Allinger, N.L. J. Am. Chem. Soc. 1989, 111, 8566.
28. Lii, J.-H.; Allinger, N.L. J. Am. Chem. Soc. 1989, 111, 8576.
29. Ponder, J.; Richards, F. J. Comput. Chem. 1986, 8, 1016.
30. Kundrot, C.; Ponder, J.; Richards, F. J. Comput. Chem. 1991, 12, 402.
31. Dudek, M.; Ponder, J. J. Comput. Chem. 1995, 16, 791.
32. Ercolessi, F.; Parrinello, M.; Tosatti, E. Phys. Mag. A 1988, 58, 213.
33. Rappe, A.K.; Goddard, W.A., III. J. Phys. Chem. 1991, 95, 3358.
34. Baxter, R.; Zerbetto, F. In preparation.
35. Quantification and peak analysis performed using the curve-fitting routines provided by Scienta showed agreement with Winspec results within ±5% allowing intercomparison of data and trends.
36. Riga, J.; Pireaux, J.-J.; Verbist, J. Mol. Phys. 1977, 34, 131.
37. Beamson, G.; Briggs, D. High-Resolution XPS of Organic Polymers; The Scienta ESCA300 Database; John Wiley & Sons Ltd.: Chichester 1992.
38. The π-π* shake-up intensity was included in the phenyl peak. For precise analysis, a carbonyl carbon shake-up should also be included. However, as its intensity is predicted to be low (< 10%), we neglected its contribution.
39. Saliba, N.; Parker, D.H.; Koel, B.E. Surf. Sci. 1998, 410, 270.
40. Krozer, A.; Rodah, M. J. Vac. Sci. Technol. A 1997, 15, 1704.
41. Takamatsu, S.; Ishi-i, M.; Imagawa, M.; Kinbara, H.; Kibuta, T.; Fukushima, T. Catal. Soc. Jpn. 1992, 34, 126.
42. Fustin, C.A.; Rudolf, P.; Taminiaux; A.F.; Zerbetto, F.; Leigh, D.A.; Caudano, R. Thin Solid Films 1998, 327-329, 321.
43. Fustin, C.A.; Gouttebaron, R.; Caudano, R.; Rudolf, P.; Leigh, D.A.; Fanti, M.; Krug, A.; Zerbetto, F. Submitted for publication.
44. Johnston, A.G.; Leigh, D.A.; Pritchard, R.J.; Deegan, M.D. Angew. Chem., Int. Ed. Engl. 1995, 34, 1209.
45. Czanderna, A.W.; King, D.E.; Spaulding, D. J. Vac. Sci. Technol. A 1991, 9, 2607.
46. Biscarini, F.; Gebauer, W.; Di Domenica, D.; Zamboni, R.; Pascual, J.I.; Leigh, D.A.; Murphy, A.; Tetard, D. Synth. Met. 1999, 102, 1466.
47. Whelan, C.M.; Cecchet, F.; Clarkson, G.J.; Leigh, D.A.; Caudano, R.; Rudolf, P. Surf. Sci. 2001, 474, 71.
48. Bellamy, L.J. The Infrared Spectra of Complex Molecules; Methuen and Co. Ltd.: London, 1966.
49. Socrates, G. Infrared Characteristic Group Frequencies, John Wiley & Sons: Chichester, 1980.
50. Netzer, F.P. Langmuir 1991, 7, 2544.
51. Weiss, K.; Gebert, S.; Wuhn, M.; Wadephol, H.; Woll, C. J. Vac. Sci. Technol. A 1998, 16, 1017.
52. Chtaib, M. Thiry, P.A.; Pireaux, J.-J.; Delrue, J.P.; Caudano, R. Surf. Sci. 1985, 162, 245.
53. Chtaib, M.; Thiry, P.A.; Delrue, J.P.; Pireaux, J.-J.; Caudano, R. J. Electron Spectrosc. Relat. Phenom. 1983, 29, 293.
54. Ibach, H.; Mills, D.L. Electron Energy Loss Spectroscopy and Surface Vibrations; Academic: London, 1982.