Hydrogen evolution reaction on electrodes: Influence of work function, dipolar adsorption, and desolvation energies

Journal of Physical Chemistry B

Volumn 106, Issue 34, 2002, Pages 8681-8688

  Harinipriya, S ^a   Sangaranarayanan, M V ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY MADRAS   (India)

Author keywords

[No Author keywords available]

Indexed keywords

WORK FUNCTION;

ADSORPTION; CHEMICAL BONDS; CURRENT DENSITY; FREE ENERGY; HYDROGEN; SOLVENTS;

ELECTROCHEMICAL ELECTRODES;

EID: 0037194923     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp012399z     Document Type: Article

References (48)

1. See, for example: Bard, A.J.; Faulkner, L.R. Electrochemical methods Fundamentals and Applications, 2nd ed.; John Wiley and Sons: New York, 2001; p 91.
2. (a) The well-known Anderson-Newns Hamiltonian has been extensively investigated in this context. See, for example: Smith, B.B.; Hynes. J.T. J. Chem. Phys. 1993, 99, 6517 and references therein.
3. (b) See, for example, Khan, S.U.M. In Modern aspects of electrochemistry; Bockris, J.O'M., Ed.; Plenum Press: New York, 1997; No. 32, p 71 and references therein.
4. (c) Schmickler, W. Annual reports on the progress of chemistry; The Royal Society of Chemistry: London, 1998; Vol. 95, Section C and references therein.
5. (a) Kelsall, G.H. In Techniques in Electrochemistry, Corrosion and metal finishing - A Handbook; Kuhn, A.T., Ed.; John Wiley and Sons: New York, 1987; Chapter 6.
6. (b) Trasatti, S. J. Electroanal. Chem. 1972, 39, 163.
7. (c) Rutschi, P.; Delahay, P. J. Chem. Phys. 1955, 23, 195.
8. (d) Trassati, S. J. Electroanal. Chem. 1971, 33, 351.
9. (a) Hamann, C.H.; Hamnett, A.; Vielstich, W. Electrochemistry; Wiley-VCH publications: New York, 1998.
10. (b) Bockris, J.O'M.; Reddy, A.K.N. Modern Electrochemistry, 2nd ed.; Kluwer Academic/Plenum Publishers: New York, 2000; Vol. 2B, p 1688.
11. See for example, MacDonald, D.D. Transient techniques in electrochemistry; Plenum Press: New York, 1977.
12. (a) Srinivasan, S.; Wroblowa, H.; Bockris, J.O'M. Adv. Catal. 1967, 17, 351.
13. (b) Vijh, A.K. J. Electrochem. Soc. 1971, 118, 1963.
14. (c) Kita, H. J. Electrochem. Soc. 1966, 113, 1095.
15. (d) Conway, B.E. Electrochemical Supercapacitors - Scientific Fundamentals and Technological Applications; Kluwer Academic/Plenum Publishers: New York, 1999; Chapter 3.
16. (a) Sakata, T. Bull. Chem. Soc. Jpn. 2000, 73, 299.
17. + is considered to be less. This distinction does not arise here insofar as the microscopic origin of the transition state is not considered, and consequently, the present analysis is strictly phenomenological.
18. Abruna, H.D. Electrochemical Interfaces; Cornell University: Ithaca, New York, 1991.
19. (a) Saradha, R.; Sangaranarayanan, M.V. J. Phys. Chem. B 1998, 102, 5099; 1998, 102, 5468.
20. (a) Saradha, R.; Sangaranarayanan, M.V. J. Phys. Chem. B 1998, 102, 5099; 1998, 102, 5468.
21. (b) Parsons, R.; Bockris, J.O'M. Trans. Faraday Soc. 1951, 47, 914.
22. (c) See, for example, Keizer, J. Statistical thermodynamics of non-equilibrium processes; Springer-Verlag: Berlin, 1987, p 238.
23. th ed.; Oxford University Press: Oxford, U.K., 1994.
24. (a) Carey, F.A.; Sundberg, J. Advanced Organic Chemistry, 3rd ed., Plenum Press: New York, 1990; Part B.
25. (b) Bockris, J.O'M.; Reddy, A.K.N.; Gamboa-Aldeco, M. Modern Electrochemistry, 2nd ed.; Kluwer Academic/Plenum Publishers: New York, 2000; Vol. 2A, pp 1191 and 1192.
26. 0 of electron-transfer reactions at electrode surfaces has however not yet been accomplished.
27. 0 of electron-transfer reactions at electrode surfaces has however not yet been accomplished.
28. Schmickler, W. Interfacial Electrochemistry; Oxford University Press: London, 1996; p 256.
29. Bockris, J.O'M.; Reddy, A.K.N. Modern electrochemistry; Plenum Publishing Corporation: NewYork, 1973; Vol. 2, Chapters 2, 7, 8, 10, and 11.
30. Mingos, D.M.P. Essentials of inorganic chemistry 1; Oxford Science Publications, Oxford University Press: London, 1995; p 11.
31. CRC Handbook of solid state electrochemistry; Gellings, P.J., Bouwmeester, H.J.M., Eds.; CRC Press: NewYork, 1996; pp 15 and 16.
32. (a) Conway, B.E. Theory and principles of electrode processes; Ronald Press Company: New York, 1965; Vol 1.
33. (b) Bockris, J.O'M., Conway, B.E., Eds. Modern aspects of Electrochemistry; Butterworths Scientific Publications: London, 1956; p 71.
34. (c) Dogonadze, R.R.; Krishtalik, L.I.; Pleskov, Yu. V. Elektrokhimiya 1974, 10, 507.
35. th ed.; CRC Press Inc.: Boca Raton, FL, 1987.
36. Pauling, L. The Nature of Chemical Bond, 3rd ed.: Cornell University Press: Ithaca, New York, 1960; p 92.
37. (a) Bockris, J.O'M.; Conway, B.E. J. Chem. Phys. 1957, 26, 532.
38. (b) Calvo, E.J. In Electrode Kinetics: Principles and methodology; Bamford, C.H., Compton, R.G., Eds.; Comprehensive Chemical Kinetics, Vol. 26; Elsevier: Amsterdam, 1986; p 54.
39. Krishtalik, L.I. In Advances in Electrochemistry and Electrochemical Engineering; Delahay, P., Ed.; Interscience: New York, 1970; Vol. 7.
40. Aray, Y.; Rodriguez, J.; Vega, D.; Rodriguez, N.E.; Arias, Angew. Chem., Int. Ed. 2000, 39, 3810.
41. (a) Levich, V.G. Adv. Electrochem. Electrochem. Eng. 1966, 4, 249.
42. (b) Levich, V.G. In Physical Chemistry; An advanced treatise; Eyring, H., Ed.; Academic press, New York, 1970; Vol. 9B, Chapter 12.
43. Dogonadze, R.R. In Reactions of molecules at electrodes; Hush, N.S., Ed.; Wiley Interscience: New York, 1971; Chapter 3 and references therein.
44. Saradha, R.; Sangaranarayanan, M.V. Unpublished results.
45. Straus, B.J.; Calhoun, A.; Gregory, A.V. J. Chem. Phys. 1995, 102, 529 and references therein.
46. Rose, A.D.; Benjamin, I. J. Chem. Phys. 1994, 100, 3534 and references therein.
47. Harinipriya, S.; Sangaranarayanan, M.V. J. Chem. Phys. 2001, 115, 6173.
48. Blowers, P.; Mazel, R. AIChE J. 2000, 46, 2041 and references therein.