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A part of this work, including the preparation of 8d, was presented at the 78th National Meeting of the Chemical Society of Japan, Funabashi, March 2000, Abstr., No. 2G310. Recently, Oehme and co-workers reported the preparation of intramolecularly donor-stabilized silenes: (a) Mickoleit, M.; Schmohl, K.; Kempe, R.; Oehme, H. Angew. Chem., Int. Ed. 2000, 39, 1610; (b) Mickoleit, M.; Kempe, R.; Oehme, H. Chem. Eur. J. 2001, 7, 987.
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31P NMR spectroscopy. However, an attempted isolation of the corresponding compound failed. We tentatively assign the signal to [2,4-di-t-butyl-6-(dimethylamino)phenyl](9-fluorenylidene)phosphine.
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See also, Ref. 12
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An analogous cyclization reaction has recently been reported: (a) Kobayashi, J.; Goto, K.; Kawashima, T. J. Am. Chem. Soc. 2001, 123, 3387; (b) Kobayashi, J.; Goto, K.; Kawashima, T.; Schmidt, M. W.; Nagase, S. J. Am. Chem. Soc. 2002, 124, 3703. See also, Ref. 12.
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