Condition monitoring of a thermally aged elastomer by 1H-NMR T2 relaxation measurements of solvent-swelled samples

Journal of Applied Polymer Science

Volumn 86, Issue 14, 2002, Pages 3636-3641

  Assink, Roger A ^a   Celina, Mathew ^a   Minier, Leanna M ^a  

^a SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

Ageing; Degradation; NMR; Polybutadiene; Solution properties

Indexed keywords

AGING OF MATERIALS; CONDITION MONITORING; CROSSLINKING; ELASTIC MODULI; MONITORING; NUCLEAR MAGNETIC RESONANCE; OXIDATION; POLYBUTADIENES; SOLVENTS; SWELLING;

PROPELLANT BINDERS; THERMALLY AGED ELASTOMERS;

ELASTOMERS;

AGING; DEGRADATION; ELASTOMER; POLYMER SOLUTION; RELAXING; TEMPERATURE EFFECT; TENSILE PROPERTY;

EID: 0037184617     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/app.11289     Document Type: Article

References (14)

1. Celina, M.; Graham, A.C.; Gillen, K.T.; Assink, R.A.; Minier, L.M. Rubber Chem Technol 2000, 73, 678.
2. Assink, R.A.; Lang, D.P.; Celina, M. J Appl Polym Sci 2001, 81, 453.
3. Harris, D.J.; Assink, R.A.; Celina, M. Macromolecules 2001, 34, 6695.
4. Farrar, T.C.; Becker, E.D. Pulse and Fourier Transform NMR; Academic: New York, 1971.
5. Simon, G.; Baumann, K.; Gronski, W. Macromolecules 1992, 25, 3624.
6. Menge, H.; Hotopf, S.; Ponitzsch, S.; Richter, S.; Arndt, K.F.; Schneider, H.; Heuert, U. Polymer 1999, 40, 5303.
7. Litvinov, V.M.; Barendswaard, W.; van Duin, M. Rubber Chem Technol, 1998, 71, 105.
8. Rodriguez, F. Principles of Polymer Systems; Hemisphere: New York, 1989.
9. Wise, J.; Gillen, K.T.; Clough, R.L. Polym Degrad Stab 1995, 49, 403.
10. Lu, Y.C.; Kuo, K.K. Thermochim Acta 1996, 275, 181.
11. Chen, J.K.; Brill, T.B. Combust Flame 1991, 87, 217.
12. Gillen, K.T.; Celina, M.; Clough, R.L.; Wise, T. Trends Polym Sci 1997, 5, 250.
13. Wise, J.; Gillen, K.T.; Clough, R.L. Polymer 1997, 38, 1929.
14. Burrel, H. In Polymer Handbook; Brandrup, J.; Immergut, E.H., Eds.; Wiley: New York, 1975.