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Examples of de novo syntheses: (a) Ko, S. Y.; Lee, A. W. M.; Masamune, S.; Reed, L. A.; Sharpless, K. B.; Walker, F. J. Science 1983, 220, 949-51.
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Selected examples: (a) Aicher, T. D.; Buszek, K. R.; Fang, F. G.; Forsyth, C. J.; Jung, S. H.; Kishi, Y.; Scola, P. M. Tetrahedron Lett. 1992, 33, 1549-52.
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and references therein
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Transannular stereoelectronic effects on reactions involving tetrahydropyran ring systems have been noted previously: Romero, J. A. C.; Tabacco, S. A.; Woerpel, K. A. J. Am. Chem. Soc. 2000, 122, 168-69 and references therein.
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31
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0043048446
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note
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2H]-L-arabinoside. It should be mentioned that additions to the minor α-epoxide isomer also proceeded with inversion at C5 to yield the corresponding D-gluco derivatives.
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32
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0042547492
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note
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1H NMR coupling constants of both the major and minor stereoisomers, supplemented by nuclear Overhauser effect experiments (see Supporting Information).
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36
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(c) Best, W. M.; Ferro, V.; Harle, J.; Stick, R. V.; Tilbrook, D. M. G. Aust. J. Chem. 1997, 50, 463-72.
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