Two-dimensional polymerization in Langmuir films: A PM-IRRAS study of octadecyltrimethoxysilane monolayers

Langmuir

Volumn 18, Issue 24, 2002, Pages 9158-9163

  Blaudez, D ^a   Bonnier, M ^c   Desbat, B ^b   Rondelez, F ^b  

^a UMR 5798   (France)

^b UNIVERSITÉ DE BORDEAUX   (France)

^c INSTITUT CURIE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; CHEMICAL BONDS; ELECTROMAGNETIC FIELD EFFECTS; INFRARED SPECTROSCOPY; INTERFACES (MATERIALS); LANGMUIR BLODGETT FILMS; MONOLAYERS; PHASE DIAGRAMS; POLYMERIZATION;

ALIPHATIC CHAINS; OCTADECYLTRIMETHOXYSILANE; POLARIZATION-MODULATED INFRARED REFLECTION ABSORPTION SPECTROSCOPY; SILANOL GROUPS; TWO DIMENSIONAL POLYMERIZATION;

ORGANIC COMPOUNDS;

EID: 0037180685     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la0257642     Document Type: Article

References (30)

1. Göbel, H. D.; Gaub, H. E.: Möhwald, H. Chem. Phys. Lett. 1987, 138, 441-446.
2. Linden, M.; Slotte, J. P.; Rosenholm, J. B. Langmuir 1996, 12, 4449-4454.
3. Carino, S. R.; Tostmann, H.; Underhill, R. S.; Logan, J.; Weerasekera, G. ;Culp, J.; Davidson, M.; Duran, R. S. J. Am. Chem. Soc. 2001, 123, 767-768.
4. Fontaine, P.; Goldmann, M.; Rondelez, F. Langmuir 1999, 15, 1348-1352.
5. Parikh, A. N.; Allara, D. L.; Ben Azouz, I.; Rondelez, F. J. Phys. Chem. 1994, 98, 7577-7590.
6. Brzoska, J. B.; Ben Azouz, I.; Rondelez, F. Langmuir 1994, 10, 4367-4373.
7. Peltonen, J. P. K.; He, P.; Linden, M.; Rosenholm, J. B. J. Phys. Chem. 1994, 98, 12403-12409.
8. Huilin, Z.; Weixing, L.; Shufang, Y.; Pingsheng, H. Langmuir 2000, 61, 2797-2801.
9. Barton, S. W.; Goudot, A.; Rondelez, F. Langmuir 1991, 1, 1029-1030.
10. Miyano, K.; Veyssié, M. Phys. Rev. Lett. 1984, 52, 1318-1320.
11. Vidon, S.; Leblanc, R. M. J. Phys. Chem. B 1998, 102, 1279-1286.
12. Mitchell, M. L.; Dluhy, R. A. J. Am. Chem. Soc. 1988, 110, 712-718 and references therein.
13. Blaudez, D.; Buffeteau, T.; Cornut, J.-C.; Desbat B.; Escafre, N.; Pézolet, M.; Turlet, J.-M. Appl. Spectrosc. 1993, 47, 869-874.
14. Blaudez, D.; Turlet, J.-M.; Dufourcq, J.; Bard, D.; Buffeteau, T.; Desbat, B. J. Chem. Soc., Faraday Trans. 1996, 92, 525-530.
15. Buontempo, J. T.; Rice, R. A. J. Chem. Phys. 1993, 99, 7030-7037.
16. Flach, C. R.; Brauner, J. W.; Mendelsohn, R. Biophys. J. 1993, 65, 1994-2001.
17. Tasumi, M.; Shimanouchi, T. J. Chem. Phys. 1965, 43, 1245-1258.
18. Snyder, R. G.; Hsu, S. L.; Krimm, S. Spectrochim. Acta 1978, 34A, 395-406.
19. Buffeteau, T.; Blaudez, D.; Péré, E.; Desbat, B. J. Phys. Chem. B 1999, 103, 5020-5027.
20. Parikh, A. N.; Schivley, M. A.; Koo, E.; Seshadri, K.; Aurentz, D.; Mueller, K.; Allara, D. L. J. Am. Chem. Soc. 1997, 119, 3135.
21. -1 peak. For vertical chains its transition moment is at 35° from the surface normal, which is close to the angle of 39° at which the PM-IRRAS signal vanishes. Another argument for neglecting this contribution is given by the absence of signal when the trimethoxysilane headgroups are converted into trihydroxysilane headgroups by hydrolysis (see curves b and c in Figure 5 of the next paragraph).
22. Socrates, G., Eds. Infrared, Characteristic Group Frequencies; John Wiley and Sons: New York, 1980; p. 128.
23. Ulman, A. Adv. Mater. 1990, 2, 573.
24. Zbinden, R. Infrared Spectroscopy of High Polymers; Academic Press: New York, 1964; Chapter 3.
25. Desbat, B.; Huong, P. V. J. Chem. Phys. 1983, 78, 6377-6384.
26. Handbook of Chemistry and Physics, 80th ed.; CRC Press: Boca Raton, 1999.
27. Desbat, B.; Oda, R. Langmuir, in press.
28. Desbat, B.; Nguyen, H. T.; Brunet, M. Soft Material, The Journal 2002, In press.
29. Sperati, C. A.; Starkweather, H. W. Adv. Polym. Sci. 1961, 2, 465.
30. Acero, A. A.; Li, M.; Rice, S. A.: Goldmann, M.; Ben Azouz, I.; Goudot, A.; Rondelez, F. J. Chem. Phys. 1993, 99, 7214-7220.