X-ray crystallographic and NMR spectroscopical characterization of intermediates in the Pd-catalyzed allylic substitution reaction with 4-substituted phosphinooxazolines. Correlation between intermediate structure and product configuration

Inorganica Chimica Acta

Volumn 337, Issue , 2002, Pages 287-298

  Zehnder, Margareta ^a   Schaffner, Silvia ^a   Neuburger, Markus ^a   Plattner, Dietmar A ^b  

^a UNIVERSITY OF BASEL   (Switzerland)

^b ETH ZURICH   (Switzerland)

Author keywords

Allylic substitution reaction; Enantioselective catalysis; Pd( 2 alkene) compounds; Pd( 3 allyl) compounds; Phosphinooxazoline ligands

Indexed keywords

ALLYLATION; CATALYSIS; ENANTIOSELECTIVITY; ENERGY DISPERSIVE X RAY ANALYSIS; ISOMERS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PLANTS (BOTANY); SUBSTITUTION REACTIONS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION ANALYSIS; X RAYS;

ALLYLIC SUBSTITUTION; CONFORMATIONAL INSTABILITY; ENANTIOSELECTIVE CATALYSIS; INTERMEDIATE STRUCTURES; PHOSPHINOOXAZOLINE LIGANDS; PRODUCT CONFIGURATION; SOLID-STATE STRUCTURES; SYN-ANTI ISOMERIZATION;

REACTION INTERMEDIATES;

2 [2 (DIPHENYLPHOSPHINO)PHENYL] 4,5 DIHYDRO 4 METHYL 4 PHENYLOXAZOLE; ACETIC ACID DERIVATIVE; ALKENE; LIGAND; MALONIC ACID DERIVATIVE; METHYL GROUP; OXAZOLE DERIVATIVE; OXAZOLINE DERIVATIVE; PALLADIUM; UNCLASSIFIED DRUG;

ALLYLATION; ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; CATALYST; CHEMICAL MODIFICATION; CRYSTAL STRUCTURE; ENANTIOSELECTIVITY; ISOMER; ISOMERISM; NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0037179989     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)00998-2     Document Type: Article

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