Spectroscopic comparison of the five-coordinate [Cu(SMeIm)(HB(3,5-iPr2pz)3)] with the four-coordinate [Cu(SCPh3)(HB(3,5-iPr2pz)3)]: Effect of coordination number increase on a blue copper type site

Inorganica Chimica Acta

Volumn 337, Issue , 2002, Pages 357-365

  Basumallick, Lipika ^a   George, Serena DeBeer ^a   Randall, David W ^a   Hedman, Britt ^a,b   Hodgson, Keith O ^a,b   Fujisawa, Kiyoshi ^c   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

^b SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^c UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

Electron transfer processes; Electronic structure; Metalloproteins; Red and blue copper centers

Indexed keywords

BOND LENGTH; CHARGE TRANSFER; COPPER; DICHROISM; ELECTRONIC STRUCTURE; PROTEINS; TEMPERATURE; X RAY ABSORPTION SPECTROSCOPY;

COPPER CENTERS; ELECTRON TRANSFER PROCESS; ELECTRONIC PERTURBATIONS; LOW-TEMPERATURE ABSORPTION; MAGNETIC CIRCULAR DICHROISMS; METALLO-PROTEINS; SPECTROSCOPIC COMPARISON; SPECTROSCOPIC TECHNIQUE;

COPPER COMPOUNDS;

COPPER COMPLEX; METALLOPROTEIN; THIOL DERIVATIVE;

ABSORPTION; ABSORPTION SPECTROSCOPY; ARTICLE; CIRCULAR DICHROISM; COVALENT BOND; ELECTRON TRANSPORT; ENERGY; GEOMETRY; INTERMETHOD COMPARISON; LOW TEMPERATURE; MOLECULAR INTERACTION; X RAY ANALYSIS;

EID: 0037179951     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01104-0     Document Type: Article

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