Acid-base and metal ion binding properties of pyridine-type ligands in aqueous solution.: Effect of ortho substituents and interrelation between complex stability and ligand basicity

Inorganica Chimica Acta

Volumn 337, Issue , 2002, Pages 131-142

  Kapinos, Larisa E ^a   Sigel, Helmut ^a  

^a UNIVERSITY OF BASEL   (Switzerland)

Author keywords

Acid base equilibria; Metal ion complexes; Ortho Substituted pyridine type ligands; Pyridine derivatives; Stability constants; Steric effects

Indexed keywords

ACIDITY; ALKALINITY; BINDING ENERGY; COPPER COMPOUNDS; LARGE SCALE SYSTEMS; LIGANDS; METAL IONS; PYRIDINE; SODIUM NITRATE; STABILITY; TRANSITION METALS;

ACID-BASE EQUILIBRIA; METAL-ION COMPLEXES; PYRIDINE DERIVATIVES; STABILITY CONSTANTS; STERIC EFFECT;

NITROGEN COMPOUNDS;

2 AMINO 5 BROMOPYRIDINE; 2 METHYL 5 BROMOPYRIDINE; 3 CHLOROPYRIDINE; 3 PICOLINE; 3,5 DIMETHYLPYRIDINE; 4 (CHLOROMETHYL)PYRIDINE; 4 BROMOPYRIDINE; ACID; AMINO ACID DERIVATIVE; BARIUM ION; BASE; CADMIUM; CALCIUM ION; COBALT; LIGAND; MAGNESIUM ION; MANGANESE; METAL ION; METHYL GROUP; NICKEL; PICOLINIC ACID; PYRIDINE DERIVATIVE; STRONTIUM; TUBERCULIN; UNCLASSIFIED DRUG; ZINC ION;

ACID BASE BALANCE; ACIDITY; ADDITION REACTION; AQUEOUS SOLUTION; ARTICLE; CALCULATION; CHEMICAL BINDING; PH; POTENTIOMETRY; TITRIMETRY;

EID: 0037179943     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)00993-3     Document Type: Article

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