Reactions of bis[dichloro(pentamethylcyclopentadienyl)rhodium(III) and -iridium(III)] with aromatic phosphine bearing a methoxy group at an ortho-position: Double insertion of 1-alkynes into a Rh-O bond

Inorganica Chimica Acta

Volumn 340, Issue , 2002, Pages 21-28

  Yamamoto, Yasuhiro ^a   Sugawara, Kenichiro ^a   Kakeya, Masateru ^a  

^a TOHO UNIVERSITY   (Japan)

Author keywords

2 Methoxyphenylphosphines; Bis dichloro(pentamethylcyclopentadienyl) rhodium(III) and iridium(III) ; Double insertion of alkyne; P O chelating ligand

Indexed keywords

CHELATION; CRYSTALS; HYDROCARBONS; IRIDIUM COMPOUNDS; LIGANDS; PHOSPHORUS COMPOUNDS;

2-METHOXYPHENYLPHOSPHINES; CHELATING LIGANDS; COORDINATION COMPLEX; DIPHENYLPHOSPHINE; DOUBLE INSERTION OF ALKYNE; PENTAMETHYLCYCLOPENTADIENYL; TRIDENTATE LIGANDS; X-RAY CRYSTAL ANALYSIS;

RHODIUM COMPOUNDS;

4 TOLYLACETYLENE; ACETYLENE DERIVATIVE; ALKYNE DERIVATIVE; BIS[DICHLORO(PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM]; BIS[DICHLORO(PENTAMETHYLCYCLOPENTADIENYL)RHODIUM]; IRIDIUM COMPLEX; PHENYLACETYLENE; PHOSPHINE; RHODIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CRYSTAL STRUCTURE; DEMETHYLATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE; STRUCTURE ANALYSIS;

EID: 0037175541     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01021-6     Document Type: Article

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