Local crystal structure around manganese in new potassium-based nanocrystalline manganese oxyiodide

Journal of Physical Chemistry B

Volumn 106, Issue 16, 2002, Pages 4053-4060

  Hwang, Seong Ju ^a   Kwon, Chai Won ^a   Portier, Josik ^a   Campet, Guy ^a   Park, Hyo Suk ^b   Choy, Jin Ho ^b   Huong, Pham V ^c   Yoshimura, Masahiro ^d   Kakihana, Masato ^d  

^a INST CHIM MATIERE COND BORDEAUX   (France)

^b Seoul National University   (South Korea)

^c UNIVERSITÉ DE BORDEAUX   (France)

^d TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CRYSTAL STRUCTURE; CURRENT DENSITY; ELECTROCHEMISTRY; ELECTROMAGNETIC WAVE ABSORPTION; GRAIN BOUNDARIES; MANGANESE COMPOUNDS; RAMAN SPECTROSCOPY; X RAY DIFFRACTION ANALYSIS; X RAY SPECTROSCOPY;

LITHIATION REACTION;

NANOSTRUCTURED MATERIALS;

EID: 0037172156     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp012704g     Document Type: Article

References (36)

1. Thackeray, M.M. Prog. Solid State Chem. 1997, 25, 1.
2. Armstrong, A.R.; Bruce, P.G. Nature 1996, 381, 499.
3. Capitaine, F.; Gravereau, P.; Delmas, C. Solid State Ionics 1996, 89, 197.
4. Koetschau, I.; Richard, M.N.; Dahn, J.R.; Soupart, J.B.; Rousche, J.C. J. Electrochem. Soc. 1995, 142, 2906.
5. Hwang, S.J.; Park, H.S.; Choy, J.H.; Campet, G. Chem. Mater. 2000, 12, 1818.
6. Gummow, R.J.; Liles, D.C.; Goodenough, J.B. Mater. Res. Bull. 1993, 28, 1249.
7. Thackeray, M.M.; David, W.I.F.; Bruce, P.G.; Goodenough, J.B. Mater. Res. Bull. 1983, 18, 469.
8. Treuil, N.; Labrugère, C.; Menetrier, M.; Portier, J.; Campet, G.; Deshayes, A.; Frison, J.C.; Hwang, S.J.; Song, S.W.; Choy, J.H. J. Phys. Chem. B 1999, 103, 2100.
9. (a) Kim, J.; Manthiram, A. Nature 1997, 390, 265.
10. (b) Manthiram, A.; Kim, J. Chem. Mater. 1998, 10, 2895.
11. (c) Kim, J.; Manthiram, A. Electrochem. Solid-State Lett. 1999, 2, 55.
12. (a) Jeong, Y.U.; Manthiram, A. Electrochem. Solid-State Lett. 1999, 2, 421.
13. (b) Jeong, Y.U.; Manthiram, A. J. Solid State Chem. 2001, 156, 331.
14. Manthiram, A.; Kim, J.; Choi, S. MRS Symp. Proc. 2000, 575, 9.
15. Xu, J.J.; Kinser, A.J.; Owens, B.B.; Amyrl, W.H. Electrochem. Solid-State Lett. 1998, 1, 1.
16. Leroux, F.; Nazar, L.F. Solid State Ionics 1997, 100, 103.
17. Chen, R.; Whittingham, M.S. J. Electrochem. Soc. 1997, 144, L64.
18. Hwang, S.J.; Park, H.S.; Choy, J.H.; Campet, G. J. Phys. Chem. B 2000, 104, 7612.
19. Hwang, S.J.; Park, H.S.; Choy, J.H.; Campet, G.; Portier, J.; Kwon, C.W.; Etourneau, J. Electrochem. Solid-State Lett. 2001, 4, A123.
20. Considering the fact that the charge capacity for the first charge process (∼ 110 mAh/g) is much smaller than that for the following discharge process, the electrochemical activity of these electrode materials is considered to originate mainly from the insertion of lithium into the as-prepared nanocrystal. In this regard, we have probed the variation of the chemical bonding nature of nanocrystalline compounds before and after chemical lithiation reaction to understand the origin of its electrochemical activity.
21. Oyanagi, H.; Matsushida, T.; Ito, M.; Kuroda, H. KEK Report 1984, 83, 30.
22. Chen, R.; Zavalij, P.; Whittingham, M.S. Chem. Mater. 1996, 8, 1275.
23. Kim, J.; Manthiram, A. Electrochem. Solid-State Lett. 1998, 1, 207.
24. Kwon, C.W.; Campet, G.; Portier, J.; Poquet, A.; Fournes, L.; Labrugere, C.; Jousseaume, B.; Toupance, T.; Choy, J.H.; Subramanian, M.A. Int. J. Inorg. Mater. 2001, 3, 211.
25. Campet, G.; Wen, S.J.; Han, S.D.; Shastry, M.C.R.; Portier, J.; Guizard, C.; Cot, L.; Xu, Y.; Salardennet, J. Mater. Sci. Eng., B 1993, 18, 201.
26. Tsang, C.; Kim, J.; Manthiram, A. J. Solid State Chem. 1998, 137, 28.
27. 1.89.
28. Horne, C.R.; Bergmann, U.; Grush, M.M.; Perera, R.C.C.; Ederer, D.L.; Callcott, T.A.; Cairns, E.J.; Cramer, S.P. J. Phys. Chem. B 2000, 104, 9587.
29. Hwang, S.J.; Park, H.S.; Choy, J.H.; Campet, G. J. Phys. Chem. B 2001, 105, 335.
30. Horne, C.R.; Bergmann, U.; Kim, J.; Striebel, K.A.; Manthiram, A.; Cramer, S.P.; Cairns, E.J. J. Electrochem. Soc. 2000, 147, 395.
31. Manceau, A.; Gorshkov, A.I.; Drits, V.A. Am. Mineral. 1992, 77, 1133.
32. Inaba, M.; Iriyama, Y.; Ogumi, Z.; Todzuka, Y.; Tasaka, A. J. Raman Spectrosc. 1997, 28, 613.
33. Jang, Y.I.; Huang, B.; Chiang, Y.M.; Sadoway, D.R. Electrochem. Solid-State Lett. 1998, 1, 13.
34. Ammundsen, B.; Jones, D.J.; Rozière, J.; Villain, F. J. Phys. Chem. B 1998, 102, 7939.
35. We have also tried to reproduce the experimental EXAFS data of lithiated derivatives on the basis of rhombohedral layered structure, but it gave poor fits and physically meaningless structural parameters.
36. Hwang, S.J.; Park, N.G.; Kim, D.H.; Choy, J.H. J. Solid State Chem. 1998, 138, 66.