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The continuity of the swelling data and shrinking kinetics for all of the samples for multiple measurements indicates that temperature variations, if any exist during the time of the brief period of gravimetric measurements, do not cause undue variations.
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note
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We attempted to degrade the gel using a strongly alkaline solution to measure the concentration of the azo moiety. However, even after several days, no degradation was observed.
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42
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0011203762
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note
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The UV-visible absorption of DMAAB was measured in DMF because it was insoluble in aqueous solutions.
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0011165677
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note
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Changes in the absorption spectrum with irradiation could not be measured as a function of temperature because of experimental constraints. Because the azobenzene moiety has a strong molar absorptivity, measurements in Figure lb had to be performed with an extremely thin film of the gel suspended in water. Increase in temperature led to warping/folding of the film, and therefore, an accurate absorption spectrum could not be obtained. The use of mechanical means to keep the gel stretched during temperature jumps is not possible because the additional mechanical stress would lead to results that would be inconsistent with the other experiments in which swelling of a "free" disklike gel was measured.
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note
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s from changes in absorbance requires a geometric description of the network wherein the fractional trans-to-cis conversion has to be related to the change in elastic free energy, which is not possible at this time.
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