Non-carbonyl-stabilized metallocarbenoids in synthesis: The development of a tandem rhodium-catalyzed bamford-stevens/thermal aliphatic claisen rearrangement sequence

Journal of the American Chemical Society

Volumn 124, Issue 42, 2002, Pages 12426-12427

  May, Jeremy A ^a   Stoltz, Brian M ^a  

^a California Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; CARBENOID; CARBONYL DERIVATIVE; ETHER DERIVATIVE; METAL; RHODIUM;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; STEREOCHEMISTRY; STEREOISOMERISM; SYNTHESIS;

EID: 0037164078     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028020j     Document Type: Article

References (26)

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15. N-aziridinyl imines in combination with catalysis have seen limited use. For examples, see: (a) Padwa, A.; Austin, D. J.; Gareau, Y.; Kassir, J. M.; Xu, S. L. J. Am. Chem. Soc. 1993, 115, 2637. (b) Sarkar, T. K.; Ghorai, B. K. J. Chem. Soc., Chem. Commun. 1992, 1184. (c) Fang, F. G.; Maier, M. E.; Danishefsky, S. J.; Schulte, G. J. Org. Chem. 1990, 55, 831.
16. N-aziridinyl imines in combination with catalysis have seen limited use. For examples, see: (a) Padwa, A.; Austin, D. J.; Gareau, Y.; Kassir, J. M.; Xu, S. L. J. Am. Chem. Soc. 1993, 115, 2637. (b) Sarkar, T. K.; Ghorai, B. K. J. Chem. Soc., Chem. Commun. 1992, 1184. (c) Fang, F. G.; Maier, M. E.; Danishefsky, S. J.; Schulte, G. J. Org. Chem. 1990, 55, 831.
17. All hydrazones were prepared from the corresponding ketones. See the Supporting Information.
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