The first total synthesis of goniothalesdiol

Tetrahedron Letters

Volumn 43, Issue 39, 2002, Pages 6983-6985

  Babjak, Matej ^a   Kapitán, Peter ^a   Gracza, Tibor ^a  

^a SLOVAK UNIVERSITY OF TECHNOLOGY   (Slovakia)

Author keywords

Goniothalesdiol; Natural products; Palladium(II) catalysis; Stereoselective oxycarbonylation

Indexed keywords

GONIOTHALESDIOL; MANNITOL; PALLADIUM; TETRAHYDROFURAN DERIVATIVE; UNCLASSIFIED DRUG;

ANNONACEAE; ARTICLE; CATALYSIS; CHEMICAL REACTION; DRUG SYNTHESIS; HYDROXYLATION; OXYCARBONYLATION; STEREOCHEMISTRY;

ANNONACEAE; GONIOTHALAMUS;

EID: 0037163269     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(02)01599-X     Document Type: Article

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21. 6, TMS): 35.7 (t, C-2), 74.4 (d, C-5), 76.4 (d, C-3), 82.2 (d, C-4), 88.1 (d, C-6), 127.1 (d, C-4′), 127.3 (d, C-2′), 127.4 (d, C-3′), 136.7 (s, C-1′), 176.0 (s, C-1).
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23. 3, TMS): 23.5 (t, C-3), 30.6 (t, C-2), 52.0 (q, OMe), 76.9 (d, C-5), 79.1 (d, C-4), 81.4 (d, C-6), 82.3 (d, C-7), 126.7 (d, C-3′, C-5′), 127.9 (d, C-4′), 128.6 (d, C-2′, C-6′), 136.8 (s, C-1′), 175.1 (s, C-1).