-
9
-
-
0005124361
-
-
2-2,2′-bipyridine; bpy=2,2′-bipyridine; phen=1,10-phenanthroline.
-
2-2,2′-bipyridine; bpy=2,2′-bipyridine; phen=1,10-phenanthroline.
-
-
-
-
10
-
-
0005217092
-
-
Depending on the surface treatment and the binding conditions, the carboxylic groups bind covalently to the surface by reacting with surface OH groups and forming ester bonds, or can form carboxylates that interact with the surface in an unknown manner. The binding mode is usually determined by IR (C=O stretching). The ester linkages provide strong electronic coupling between the complex and the semiconductor and are thought to cause the ultrafast (femtosecond) electron injection rate constants that have been measured.
-
Depending on the surface treatment and the binding conditions, the carboxylic groups bind covalently to the surface by reacting with surface OH groups and forming ester bonds, or can form carboxylates that interact with the surface in an unknown manner. The binding mode is usually determined by IR (C=O stretching). The ester linkages provide strong electronic coupling between the complex and the semiconductor and are thought to cause the ultrafast (femtosecond) electron injection rate constants that have been measured.
-
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12
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2542558270
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(a) Bakkers E.P.A.M., Roest A.L., Marsman A.W., Jenneskens L.W., de Jong-van Steensel L.I., Kelly J.J., Vanmaekelbergh D. J. Phys. Chem. B. 104:2000;7266. and references therein
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Kelly, J.J.6
Vanmaekelbergh, D.7
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Zhu, X.Y.5
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21
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0037196312
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Tripod-shaped linkers of various structure (also named caltrops, see Ref. 9c ) have been previously reported in studies of redox active molecules bound on gold electrodes: (a) Hirayama D., Takimiya K., Aso Y., Otsubo T., Hasobe T., Yamada H., Imahori H., Fukuzumi S., Sakata Y. J. Am. Chem. Soc. 124:2002;532 (b) Yao Y., Tour J.M. J. Org. Chem. 64:1999;1968 (c) Fox M.A., Whitesell J.K., McKerrow A. J. Langmuir. 14:1998;816 (d) Hu J., Mattern L. J. Org. Chem. 65:2000;2277. For tetrahedral molecules with extended arms see: (e) Aujard I., Baltaze J.-P., Baudin J.-B., Cogné E., Ferrage F., Jullien L., Perez E., Prévost V., Qian L.M., Ruel O. J. Am. Chem. Soc. 123:2001;8177.
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Hirayama, D.1
Takimiya, K.2
Aso, Y.3
Otsubo, T.4
Hasobe, T.5
Yamada, H.6
Imahori, H.7
Fukuzumi, S.8
Sakata, Y.9
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22
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0033583165
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Tripod-shaped linkers of various structure (also named caltrops, see Ref. 9c ) have been previously reported in studies of redox active molecules bound on gold electrodes: (a) Hirayama D., Takimiya K., Aso Y., Otsubo T., Hasobe T., Yamada H., Imahori H., Fukuzumi S., Sakata Y. J. Am. Chem. Soc. 124:2002;532 (b) Yao Y., Tour J.M. J. Org. Chem. 64:1999;1968 (c) Fox M.A., Whitesell J.K., McKerrow A. J. Langmuir. 14:1998;816 (d) Hu J., Mattern L. J. Org. Chem. 65:2000;2277. For tetrahedral molecules with extended arms see: (e) Aujard I., Baltaze J.-P., Baudin J.-B., Cogné E., Ferrage F., Jullien L., Perez E., Prévost V., Qian L.M., Ruel O. J. Am. Chem. Soc. 123:2001;8177.
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Yao, Y.1
Tour, J.M.2
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23
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0032001071
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Tripod-shaped linkers of various structure (also named caltrops, see Ref. 9c ) have been previously reported in studies of redox active molecules bound on gold electrodes: (a) Hirayama D., Takimiya K., Aso Y., Otsubo T., Hasobe T., Yamada H., Imahori H., Fukuzumi S., Sakata Y. J. Am. Chem. Soc. 124:2002;532 (b) Yao Y., Tour J.M. J. Org. Chem. 64:1999;1968 (c) Fox M.A., Whitesell J.K., McKerrow A. J. Langmuir. 14:1998;816 (d) Hu J., Mattern L. J. Org. Chem. 65:2000;2277. For tetrahedral molecules with extended arms see: (e) Aujard I., Baltaze J.-P., Baudin J.-B., Cogné E., Ferrage F., Jullien L., Perez E., Prévost V., Qian L.M., Ruel O. J. Am. Chem. Soc. 123:2001;8177.
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Fox, M.A.1
Whitesell, J.K.2
McKerrow, A.3
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24
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0034697186
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Tripod-shaped linkers of various structure (also named caltrops, see Ref. 9c ) have been previously reported in studies of redox active molecules bound on gold electrodes: (a) Hirayama D., Takimiya K., Aso Y., Otsubo T., Hasobe T., Yamada H., Imahori H., Fukuzumi S., Sakata Y. J. Am. Chem. Soc. 124:2002;532 (b) Yao Y., Tour J.M. J. Org. Chem. 64:1999;1968 (c) Fox M.A., Whitesell J.K., McKerrow A. J. Langmuir. 14:1998;816 (d) Hu J., Mattern L. J. Org. Chem. 65:2000;2277. For tetrahedral molecules with extended arms see: (e) Aujard I., Baltaze J.-P., Baudin J.-B., Cogné E., Ferrage F., Jullien L., Perez E., Prévost V., Qian L.M., Ruel O. J. Am. Chem. Soc. 123:2001;8177.
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Hu, J.1
Mattern, L.2
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25
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0034803928
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Tripod-shaped linkers of various structure (also named caltrops, see Ref. 9c ) have been previously reported in studies of redox active molecules bound on gold electrodes: (a) Hirayama D., Takimiya K., Aso Y., Otsubo T., Hasobe T., Yamada H., Imahori H., Fukuzumi S., Sakata Y. J. Am. Chem. Soc. 124:2002;532 (b) Yao Y., Tour J.M. J. Org. Chem. 64:1999;1968 (c) Fox M.A., Whitesell J.K., McKerrow A. J. Langmuir. 14:1998;816 (d) Hu J., Mattern L. J. Org. Chem. 65:2000;2277. For tetrahedral molecules with extended arms see: (e) Aujard I., Baltaze J.-P., Baudin J.-B., Cogné E., Ferrage F., Jullien L., Perez E., Prévost V., Qian L.M., Ruel O. J. Am. Chem. Soc. 123:2001;8177.
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Aujard, I.1
Baltaze, J.-P.2
Baudin, J.-B.3
Cogné, E.4
Ferrage, F.5
Jullien, L.6
Perez, E.7
Prévost, V.8
Qian, L.M.9
Ruel, O.10
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26
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0005119044
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in press
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(a) Galoppini E., Guo W., Zhang W., Hoertz P., Qu P., Meyer G.J. J. Am. Chem. Soc. 2002;. in press
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Galoppini, E.1
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29
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0005124362
-
-
This is defined as the distance from the Ru center to the footprint, i.e. the plane defined by the three surface-bound oxygen atoms.
-
This is defined as the distance from the Ru center to the footprint, i.e. the plane defined by the three surface-bound oxygen atoms.
-
-
-
-
30
-
-
0035936916
-
-
For conjugated linkers used to attach redox-active molecules on gold see for instance (a) Sikes H.D., Smalley J.F., Dudek S.P., Cook A.C., Newton M.D., Chidsey C.E.D., Feldberg S.W. Science. 291:2001;1519 (b) Davis W.B., Svec W.A., Ratner M.A., Wasielewski M.R. Nature. 396:1998;60.
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Sikes, H.D.1
Smalley, J.F.2
Dudek, S.P.3
Cook, A.C.4
Newton, M.D.5
Chidsey, C.E.D.6
Feldberg, S.W.7
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31
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0032487965
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-
For conjugated linkers used to attach redox-active molecules on gold see for instance (a) Sikes H.D., Smalley J.F., Dudek S.P., Cook A.C., Newton M.D., Chidsey C.E.D., Feldberg S.W. Science. 291:2001;1519 (b) Davis W.B., Svec W.A., Ratner M.A., Wasielewski M.R. Nature. 396:1998;60.
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Davis, W.B.1
Svec, W.A.2
Ratner, M.A.3
Wasielewski, M.R.4
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32
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0001546712
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K. Sonogashira. Oxford: Pergamon Chapter 25
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(a) Coupling Reactions Between sp Carbon Centers. Sonogashira K., Comprehensive Organic Synthesis. Vol. 3:1991;551-561 Pergamon, Oxford. Chapter 25
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45
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-
0003924674
-
-
New York: Marcel Dekker
-
The data for pyrene and antracene in Table 1 were determined experimentally and are close to values reported in literature: Murov S.L., Carmichael I., Hug G.L. Handbook of Photochemistry. 1993;Marcel Dekker, New York.
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(1993)
Handbook of Photochemistry
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Murov, S.L.1
Carmichael, I.2
Hug, G.L.3
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48
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0003768971
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A.J. Bard, & L.R. Faulkner. New York: Wiley
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Bard A.J., Faulkner L.R., Electrochemical Methods. 2001;811 Wiley, New York.
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Electrochemical Methods
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