Determination of the ethylene oxide content of polyether polyols by low-field 1H nuclear magnetic resonance spectrometry

Analytica Chimica Acta

Volumn 472, Issue 1-2, 2002, Pages 133-140

  Nordon, Alison ^a   Meunier, Céline ^a   Carr, Robert H ^b   Gemperline, Paul J ^c   Littlejohn, David ^a  

^a UNIVERSITY OF STRATHCLYDE   (United Kingdom)

^b Huntsman Polyurethanes Belgium   (Belgium)

^c EAST CAROLINA UNIVERSITY   (United States)

Author keywords

Direct exponential curve resolution algorithm; Ethylene oxide; Low field NMR spectrometry; Polyether polyols; Process analysis

Indexed keywords

ETHYLENE OXIDE; POLYETHER DERIVATIVE; POLYOL;

ACCURACY; ALGORITHM; ANALYTIC METHOD; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; INTERMETHOD COMPARISON; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; SPECTROSCOPY;

EID: 0037145785     PISSN: 00032670     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0003-2670(02)00939-X     Document Type: Article

References (17)

1. G. Woods, The ICI Polyurethanes Book, 2nd Ed., Wiley, Chichester, UK, 1990, p. 362.
2. Carr R.H., Hernalsteen J., Devos J. J. Appl. Polym. Sci. 52:1994;1015.
3. S. Siggia, J. Hanna, Quantitative Organic Analysis Via Functional Groups, 4th ed., Wiley, New York, 1979, p. 278.
4. Turley P.A., Pietrantonio A. J. Cell. Plastics. 20:1984;274.
5. LeBas C.L., Turley P.A. J. Cell. Plastics. 20:1984;194.
6. Mathias A., Mellor N. Anal. Chem. 38:1966;472.
7. Strömberg K. Process Control Qual. 9:1997;179.
8. M.A. Carey, P.A. Turley, in: Proceedings of the SPI 29th Annual Technical/Marketing Conference, 1985, p. 214.
9. Annual Book of ASTM Standards, vol. 15.05, D4875, American Society for Testing and Materials, Philadelphia, 1989, p. 1.
10. Heatley F., Luo Y.Z., Ding J.F., Mobbs R.H., Booth C. Macromolecules. 21:1988;2713.
11. G.E. Maciel, Nuclear Magnetic Resonance in Modern Technology, Kluwer Academic Publishers, Netherlands, 1994, p. 225.
12. Nordon A., McGill C.A., Littlejohn D. Analyst. 126:2001;260.
13. Workman J. Jr., Veltkamp D.J., Doherty S., Anderson B.B., Creasy K.E., Koch M., Tatera J.F., Robinson A.L., Bond L., Burgess L.W., Bokerman G.N., Ullman A.H., Darsey G.P., Mozayeni F., Bamberger J.A., Greenwood M.S. Anal. Chem. 71:1999;121R.
14. Nordon A., McGill C.A., Littlejohn D. Appl. Spectrosc. 56:2002;75.
15. Nordon A., McGill C.A., Littlejohn D. Spectrosc. Eur. 13:2001;10.
16. Windig W., Antalek B. Chemom. Intell. Lab. Syst. 37:1997;241.
17. Nordon A., Gemperline P.J., McGill C.A., Littlejohn D. Anal. Chem. 73:2001;4286.