Development of Mn(III)(Schiff base) complexes for the catalyst of olefin oxygenation to alcohols in the presence of NaBH4 [4]

Bulletin of the Korean Chemical Society

Volumn 23, Issue 10, 2002, Pages 1365-1366

  Lee, Nam Ho ^a   Byun, Jong Chul ^a   Baik, Jong Seok ^a   Han, Chung Hun ^a   Han, Sung bin ^a  

^a Jeju National University   (South Korea)

Author keywords

Mn(Schiff base) complex; Olefin Oxidation; Oxygenation

Indexed keywords

ALKENE; LIMONENE; SCHIFF BASE;

CATALYSIS; CHEMICAL REACTION; COMPLEX FORMATION; DRUG CONJUGATION; ELECTRON TRANSPORT; LETTER; LIGAND BINDING; OXIDATION; OXYGENATION; SOLUBILITY; STEREOSPECIFICITY;

EID: 0037145565     PISSN: 02532964     EISSN: None     Source Type: Journal    
DOI: 10.5012/bkcs.2002.23.10.1365     Document Type: Letter

References (5)

1. Siméndi, L. I. Catalytic Activation of Dioxygen by Metal Complexes; Kluwer Academic Publishers: Boston, 1992.
2. Lee, N. H.; Baik, J. S.; Han, S-B. Bull. Korean Chem. Soc. 1999, 20, 867, and references cited therein.
3. Byun, J. C.; Han, C. H.; Lee, N. H.; Baik, J. S. Manuscript submitted for the publication.
4. -1): 2959 (m), 2901 (m), 1628 (s), 1606 (s), 1544 (s), 1469 (s), 1444 (s), 1303 (s), 1277 (s); UV (MeOH): 374 nm.
5. 2 was undertaken by evacuation/charging procedure three times. To this was added via syringe NaBH4 (1.5 mmol, 54 mg) dissolved in 4 mL ethanol over 20 min with stirring. After the reaction mixture was stirred for 4 h at rt, it was poured into sat. NH4C1 solution and extracted with diethyl ether. The organic layer was dried, concentrated and flash chromatographed to give 1-phenyl-1-propanol (99 mg, 72% yield) as the product.